高等学校化学学报

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (12): 1896.

• 研究简报 • 上一篇    下一篇

含胺配体过渡金属络正离子与[Ni(cdc)2]2-的加合物的合成和物理性质

李金山1, 谢斌2   

  1. 1. 南开大学元素有机化学研究所, 天津, 300071;
    2. 四川轻化工学院基础部
  • 收稿日期:1995-12-29 出版日期:1996-12-24 发布日期:1996-12-24
  • 通讯作者: 李金山,男,51岁,副教授.
  • 作者简介:李金山,男,51岁,副教授.
  • 基金资助:

    国家自然科学基金

Synthesis and Physical Properties of Adducts of Transition-metal Complex Cations Containing Amine Ligands with [Ni(cdc)2]2-

LI Jin-Shan1, XIE Bin2   

  1. 1. Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071;
    2. Dept.of Basic Sciences, Sichuan Institute of Light Industry & Chemical Technology
  • Received:1995-12-29 Online:1996-12-24 Published:1996-12-24

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关键词: N-氰基亚胺基二硫代甲酸根, 加合物, 光谱, 配位

Abstract: Aseries of adducts of transition-metal complex cations containing amine ligands with [Ni(cdc)2]2-,[ML2][Ni(cdc)2] (cdc=N-cyanodithiocarbimate; M=Cu(Ⅱ), Ni(Ⅱ),Zn(Ⅱ),Mn(Ⅱ);L=en,pn,tn,dien,opda) and [Ni(en)3][Ni(cdc)2],have been synthesized by metathetical reaction between transition-metal complexes containing amine ligands and K2[Ni(cdc)2].The physical properties of these adducts were investigated.The interaction between cations and anion was discussed.

Key words: N-Cyanodithiocarbimate, Adduct, Spectrum, Coordination

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