高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (1): 79.

• 论文 • 上一篇    下一篇

芳基对硝基苯乙炔基汞的合成

张孝义, 吴向东, 秦金贵, 刘道玉   

  1. 武汉大学化学系, 武汉 430072
  • 收稿日期:1994-02-04 修回日期:1994-05-28 出版日期:1995-01-24 发布日期:1995-01-24
  • 通讯作者: 张孝义,男,25岁,硕士研究生.
  • 作者简介:秦金贵
  • 基金资助:

    攀登计划资助;国家自然科学基金

Synthesis of(4-Nitropphenylacetylenyl)(aryl)mercury

ZHANG Xiao-Yi, WU Xiang-Dong, QIN Jin-Gui, LIU Dao-Yu   

  1. Department of Chemistry, Wuhan University, Wuhan, 430072
  • Received:1994-02-04 Revised:1994-05-28 Online:1995-01-24 Published:1995-01-24

PDF (PC)

被引次数

1

摘要： 采用芳基醋酸汞或芳基氢氧化汞与对硝基苯乙炔在碱性介质中反应,合成了12种新的取代苯基对硝基苯乙炔基汞化合物。紫外可见光诸实验表明此合成反应为可逆反应。通过元素分析及IR、MS、1NMR和UV光谱对化合物结构进行了鉴定。

关键词: 有机汞化合物, 合成, 鉴定

Abstract: Aseries of new(4-nitrophenylacetylenyl)(aryl)mercury compounds were prepared by the reaction of aryl mercury acetate or aryl mercury hydroxide with 4-nitrophenylacetylene under a base condition. The results of ultraviolet absorption spectroscopic study showed that the reaction is reversible.All the compounds were characterized bv means of elementary analysis,IR,1HNMR,electronic and mass spectroscopies.

Key words: Organomercuric compound, Synthesis, Characterization

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