高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (8): 805.

• 研究论文 • 上一篇    下一篇

RE(Ⅲ)-ADP、RE(Ⅲ)-AMP配合物的合成及物性研究

彭周人, 李一志, 王流芳   

  1. 兰州大学化学系
  • 收稿日期:1988-08-23 出版日期:1990-08-24 发布日期:1990-08-24
  • 通讯作者: 彭周人

Studies on the Synthesis and Properties of Rare Earth Complexes with ADP and AMP

Peng Zhouren, Li Yizhi, Wang Liufang   

  1. Department of Chemistry, Lanzhou University, Lanzhou
  • Received:1988-08-23 Online:1990-08-24 Published:1990-08-24

摘要: 首次合成了具有生物活性的系列配合物RE(Ⅲ)-ADP(稀土-腺苷二磷酸)和RE(Ⅲ)-AMP(稀土-腺苷-磷酸)(RE=Y,La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu),根据红外、紫外、荧光、X射线衍射、元素分析、络合滴定等分析结果,研究了[RE(Ⅲ)(ADP)(H2O)3]和[RE(Ⅲ)(AMP)2(H2O)4]H两个系列配合物的化学组成和性质。

关键词: 稀土-腺苷二磷酸, 稀土-腺苷-磷酸, 配合物, 稀土

Abstract: The preparation of RE( Ⅲ )-ADP (rare earth-adenosine-5'-diphosphate) and RE( Ⅲ )-AMP(rare earth-adenosine-5'-raonophosphate) (RE = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) complexes possessing biological activities are first reported. The chemical compositions and trie properties of some of them have been elucidated on the basis of IR, UV, fluorescence, X-ray, elemental analysis and complexometric titratioh. The formulae of the complexes are [RE(Ⅲ)·(ADP)(H2O)3] and [(RE(Ⅲ)(AMP)2(H2O)4]H, respectively.

Key words: RE( Ⅲ )-ADP, RE( Ⅲ )-AMP, Complex, Rare earth

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