利用光响应钌配合物的动态配位键调控表面功能

doi:10.7503/cjcu20190655

摘要/Abstract

摘要：

综合评述了光响应钌配合物的动态配位键在调控表面功能中的应用, 介绍了以可见光或近红外光为光源的光响应钌配合物在表面图案化、控制蛋白质表面吸附及调控表面浸润性三方面的应用, 讨论了光响应钌配合物的动态配位键在动态表面构筑中的独特优势, 对其未来应用进行了展望.

关键词: 光响应钌配合物, 动态配位键, 表面功能调控

Abstract:

We introduce ruthenium complexes with photoresponsive coordination bonds for light-controlled surface functions, including light-controlled surface patterns, manipulating protein adsorption and controlling wettability. Meanwhile, the fascinating features of photoresponsive Ru-ligand dynamic coordination bonds in surface functions are presented and their future applications are prospected.

Key words: Photoresponsive ruthenium complex, Dynamic coordination bond, Control of surface function

中图分类号:

O631

黄云帅, 杨霓, 吴泽宏, 吴思. 利用光响应钌配合物的动态配位键调控表面功能[J]. 高等学校化学学报, 2020, 41(6): 1174-1178.

HUANG Yunshuai, YANG Ni, WU Zehong, WU Si. Ruthenium Complexes with Photoresponsive Coordination Bonds for Light-controlled Surface Functions ^†[J]. Chemical Journal of Chinese Universities, 2020, 41(6): 1174-1178.

图/表 4

Fig.1 Schematic diagram of photon upconversion lithography(PUCL) for the patterning of proteins[45] Polyethylene glycol, which is co-grafted with Ru complexes on the upconverting nanoparticles(UCNPs), is not shown for clarity. Copyright 2015, Wiley-VCH.

Fig.2 Schematic illustration of visible-light-controlled reconfigurable multi-functional platform(A) and the mechanism of reconfiguring surfaces via ligand substitution(B)[46] Copyright 2018, Springer Nature.

Fig.3 Schematic illustration of the rewriting surface patterns on the Ru-H2O-modified substrate using visible light(A) and the fluorescence microscopy images of the Ru-H2O-modified substrate(B), Ru-MeSC2H4-FITC-modified substrate(C), patterned substrate consisting of a Ru-MeSC2H4-FITC-modified part(green) and a Ru-H2O-modified part(dark)(D) and patterned substrate consisting of a Ru-MeSC2H4-FITC-modified part(green) and a Ru-MeSC2H4-RhB modified part(red)(E)[46] Copyright 2018, Springer Nature.

Fig.4 Schematic illustrations of the conversion of a protein-resistant surface into a protein-adsorptive surface(A) and the reversible hydrophilic-to-superhydrophobic transitions based on visible-light-controlled metal-ligand coordination surface with light(B)[46] Copyright 2018, Springer Nature.

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