高等学校化学学报 ›› 2020, Vol. 41 ›› Issue (6): 1174.doi: 10.7503/cjcu20190655
• 庆祝《高等学校化学学报》复刊40周年专栏 • 上一篇 下一篇
收稿日期:
2019-12-11
出版日期:
2020-06-10
发布日期:
2020-02-10
通讯作者:
吴思
E-mail:siwu@ustc.edu.cn
基金资助:
HUANG Yunshuai,YANG Ni,WU Zehong,WU Si*()
Received:
2019-12-11
Online:
2020-06-10
Published:
2020-02-10
Contact:
Si WU
E-mail:siwu@ustc.edu.cn
Supported by:
摘要:
综合评述了光响应钌配合物的动态配位键在调控表面功能中的应用, 介绍了以可见光或近红外光为光源的光响应钌配合物在表面图案化、 控制蛋白质表面吸附及调控表面浸润性三方面的应用, 讨论了光响应钌配合物的动态配位键在动态表面构筑中的独特优势, 对其未来应用进行了展望.
中图分类号:
TrendMD:
黄云帅, 杨霓, 吴泽宏, 吴思. 利用光响应钌配合物的动态配位键调控表面功能. 高等学校化学学报, 2020, 41(6): 1174.
HUANG Yunshuai, YANG Ni, WU Zehong, WU Si. Ruthenium Complexes with Photoresponsive Coordination Bonds for Light-controlled Surface Functions . Chem. J. Chinese Universities, 2020, 41(6): 1174.
Fig.1 Schematic diagram of photon upconversion lithography(PUCL) for the patterning of proteins[45] Polyethylene glycol, which is co-grafted with Ru complexes on the upconverting nanoparticles(UCNPs), is not shown for clarity. Copyright 2015, Wiley-VCH.
Fig.2 Schematic illustration of visible-light-controlled reconfigurable multi-functional platform(A) and the mechanism of reconfiguring surfaces via ligand substitution(B)[46] Copyright 2018, Springer Nature.
Fig.3 Schematic illustration of the rewriting surface patterns on the Ru-H2O-modified substrate using visible light(A) and the fluorescence microscopy images of the Ru-H2O-modified substrate(B), Ru-MeSC2H4-FITC-modified substrate(C), patterned substrate consisting of a Ru-MeSC2H4-FITC-modified part(green) and a Ru-H2O-modified part(dark)(D) and patterned substrate consisting of a Ru-MeSC2H4-FITC-modified part(green) and a Ru-MeSC2H4-RhB modified part(red)(E)[46] Copyright 2018, Springer Nature.
Fig.4 Schematic illustrations of the conversion of a protein-resistant surface into a protein-adsorptive surface(A) and the reversible hydrophilic-to-superhydrophobic transitions based on visible-light-controlled metal-ligand coordination surface with light(B)[46] Copyright 2018, Springer Nature.
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