高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (4): 345.

• 研究论文 • 上一篇    下一篇

稀土吲哚-3-乙酸和吲哚-3-丁酸配合物的合成、表征及成键特性研究

王则民, 傅楚瑾, 曹锦荣, 卢峰   

  1. 上海师范大学化学系
  • 收稿日期:1988-08-30 出版日期:1990-04-24 发布日期:1990-04-24
  • 通讯作者: 王则民

Studies on the Synthesis and Characterization and Bonding Specificity of Rare Earth ( Ⅲ) Complexes with Indole-3-Acetic Acid and Indole-3-butanoic Acid

Wang Zemin, Fu Chujin, Cao Jinrong, Lu Feng   

  1. Department of Chemistry, Shanghai Normal University, Shanghai
  • Received:1988-08-30 Online:1990-04-24 Published:1990-04-24

PDF (PC)

被引次数

34

摘要： 在乙醇水溶液体系中合成了8种新的稀土吲哚-3-乙酸和吲哚-3-丁酸配合物,其通式为Ln(lA)3·2H2O和Ln(IB)3·2H2O(Ln=La,Nd,Sm,Er;IA=C10H8NO2;IB=C12H12NO2)。用元素分析、电导测定、电子吸收光谱、红外光谱、X光电子能谱和热重-差热分析确定了配合物的组成和成键特性。

关键词: 稀土, 吲哚-3-乙酸, 吲哚-3-丁酸, 配合物

Abstract: Eight new solid complexes of rare earth ( Ⅲ ) with indole-3-butanoicacid and indole-3-bu-tanoic acid were synthesized in ethanol-water soluton. The new complexes have the composition Ln (IA)3·2H2Oand Ln(IB)3·2H2O(Ln = La,Nd,Sm,Er,IA = C10H8NO2, IB = C12H12NO2). The electronic spectra of the complexes were observed. The molar conductance data show that the complexes are non-electrolyte. IRspectra and XPSmeasurements indicate the unidentate coordination mode of carboxylate ions to rare earth (Ⅲ ) ion in Ln(IA)3 · 2H2Ocompounds and the bidentate coordination mode of carboxylate ions in Ln(IB)3 · 2H2Ocompounds, also show that nitrogen atoms in indole-3-acetates are coordinated, but nitrogen atoms in indole-3-butanoates are uncoordinated. The TG-DTAdata show that the complexes are all relatively stable thermally.

Key words: Rare earth, Indole-3-acetic acid, Indole-3-butanoic acid, Complexes

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