高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (1): 26.

• 研究论文 • 上一篇    下一篇

仿生性杀虫剂杀虫单与溴的氧化-还原反应研究

张长庚1, 罗红卫1, 犹莹1, 王欣2, 李海泉2   

  1. 1. 贵州大学化学系;
    2. 兰州大学分析测试中心
  • 收稿日期:1988-04-28 出版日期:1990-01-24 发布日期:1990-01-24
  • 通讯作者: 张长庚
  • 基金资助:

    贵州省自然科学基金

Investigation on Oxidation-Reduction Reaction of Biomimetic Insecticide [(CH3)2NHCH(CH2S2O3,)2Na·H2O] with Bromine

Zhang Changgeng1, Luo Hongwei1, You Ying1, Wang Xin2, Li Haiquan2   

  1. 1. Department of Chemistry, Guizhou University, Guiyang;
    2. Analytical mi Testing Center of Lanzhou University, Lanzhou
  • Received:1988-04-28 Online:1990-01-24 Published:1990-01-24

摘要: 用X射线单晶结构分析、质谱、库仑滴定和重量分析法研究了仿生性杀虫剂与澳的反应。研究表明该反应为均相反应,反应中有6个电子转移。

关键词: 仿生性杀虫剂, 晶体结构, 质谱, 库仑滴定, 电子转移数

Abstract: Oxidation-reduction reaction of biomimetic insecticide (CH3)2NHCH(CH2S2O3)2Na .H2Owith bromine has been investigated by X-ray single crystal structure analysis ,mass spectrometry, gravimetric analysis and coulometric titration. Our research shows that the reaction is homogeneous, there is transfer of six electrons in the reaction.

Key words: Biomimetic insecticide, Crystal structure, Mass spectrometry, Coulometric titration, Electron transfer number

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