高等学校化学学报 ›› 2020, Vol. 41 ›› Issue (12): 2577-2586.doi: 10.7503/cjcu20200414

• 庆祝《高等学校化学学报》复刊40周年专栏 • 上一篇    下一篇

稀土-钛氧簇合物的研究进展

李观俊, 龙腊生, 孔祥建(), 郑兰荪   

  1. 厦门大学化学化工学院化学系, 固体表面物理化学国家重点实验室, 能源材料化学协同创新中心, 厦门 361005
  • 收稿日期:2020-07-01 出版日期:2020-12-10 发布日期:2020-12-09
  • 通讯作者: 孔祥建 E-mail:xjkong@xmu.edu.cn
  • 基金资助:
    国家自然科学基金(批准号(21871224);21673184, 21721001)资助

Recent Advances in Lanthanide-titanium-oxo Clusters

LI Guanjun, LONG Lasheng, KONG Xiangjian(), ZHENG Lansun   

  1. Collaborative Innovation Center of Chemistry for Energy Materials,State Key Laboratory of Physical Chemistry of Solid Surface,Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China
  • Received:2020-07-01 Online:2020-12-10 Published:2020-12-09
  • Contact: KONG Xiangjian E-mail:xjkong@xmu.edu.cn
  • Supported by:
    ? Supported by the National Natural Science Foundation of China(21871224)

摘要:

稀土-钛氧簇合物作为团簇化学的一个新分支, 不但结合了稀土和钛离子的特性, 而且由于二者的协同效应而表现出优异的光、 电、 磁和催化性能.本文综合评述了不同配体稀土-钛氧簇合物的合成与结构, 介绍了稀土-钛氧簇合物的代表性成果, 并对其合成策略和发展前景进行了总结和展望.

关键词: 稀土-钛氧簇合物, 合成, 结构, 荧光, 光催化

Abstract:

As a new branch of cluster chemistry, lanthanide-titanium-oxo clusters not only integrate the cha-racteristics of lanthanide and titanium ions, but also often show a synergistic effect of the two elements, so they usually have excellent optical, electoral, magnetic and catalytic properties. The lanthanide-titanium-oxo cluters attract more attention because its accurate structure model is more conducive to understand the relationship between structure and activity. In this paper, the synthesis and structures of lanthanide-titanium-oxo clusters are outlined based on different ligands and the representative properties are introduced. The synthetic strategies and development prospects of lanthanide-titanium-oxo clusters are prospected. It is hoped that this review can provide insight into future research on lanthanide-titanium-oxo clusters.

Key words: Lanthanide-titanium-oxo cluster, Synthesis, Structure, Luminescence, Photocatalysis

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