Photopromoted Carbonylation of Olefins and Carbon Dioxide Under Ambient Conditions

Abstract

Abstract: It was found that photopromoted carbonylation of olefins and CO₂ under ambient conditions could be catalyzed by Co(OAc)₂, Co(acac)₂, CoSalen, Cobalt picolinic ester and[Co(14)-4,11-diene-N₄]I₂[5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieneatocobalt(Ⅱ)]. The carbonylation of cyclohexene gave some by-products of cyclo-C₆H₁₁-CH₂OH, cyclo-C₆H₁₁-CHO and cyclo-C₆H₁₁-COCH₃, which were established by labelling studies with ¹³CO₂,¹³CH₃OH, CD₃OD and CD₃COCD₃. CH₃(CH₂)₇-CH₂OH, CH₃(CH₂)₇-CHO and CH₃(CH₂)₇-COCH₃ were also confirmed as the by-products of carbonylation of 1-octene.

Key words: Carbon dioxide, Photopromotion, Carbonylation, Ambient conditions, Isotope experimental

CLC Number:

O643
TQ 42

TrendMD:

YIN Jing-Mei, ZHOU Guang-Yun, QI Chun-Qiao, GAO Da-Bin, JIA Ying-Ping, WANG Xiang-Sheng . Photopromoted Carbonylation of Olefins and Carbon Dioxide Under Ambient Conditions[J]. Chem. J. Chinese Universities, 2004, 25(7): 1285.

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Photopromoted Carbonylation of Olefins and Carbon Dioxide Under Ambient Conditions

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