Terpolymerization of Carbon Dioxide, Propylene Oxide and Cyclohexene Oxide Catalyzed  by Rare-earth Ternary Catalyst

Chem. J. Chinese Universities ›› 2005, Vol. 26 ›› Issue (12): 2360.

• Articles • Previous Articles Next Articles

Terpolymerization of Carbon Dioxide, Propylene Oxide and Cyclohexene Oxide Catalyzed by Rare-earth Ternary Catalyst

XIE Dong, QUAN Zhi-Long, WANG Xian-Hong^*, ZHAO Xiao-Jiang, WANG Fu-Song

Polymer Material Engineering Lab, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2004-12-06 Online:1905-03-14 Published:1905-03-14
Contact: WANG Xian-Hong;E-mail:xhwang@ciac.jl.cn

Abstract

Abstract:

Y(CCl₃COO)₃/ZnR₂/Glycerol was used for the terpolymerization of carbon dioxide(CO₂), propylene oxide(PO), and cyclohexene oxide(CHO). The cyclohexene carbonate content and the syndiotactic structure of the terpolymer increases with the increase of CHO content.The terpolymer is a random block copolymer of poly(propylene carbonate) and poly(cyclohexene carbonate), and the introduction of CHO in the terpolymer could significantly improve the thermal stability.

Key words: Carbon dioxide; Propylene oxide; Cyclohexene oxide; Terpolymerization; Rare-earth ternary catalyst, Carbon dioxide, Propylene oxide, Cyclohexene oxide, Terpolymerization, Rare-earth ternary catalyst

CLC Number:

O631

TrendMD:

XIE Dong, QUAN Zhi-Long, WANG Xian-Hong, ZHAO Xiao-Jiang, WANG Fu-Song. Terpolymerization of Carbon Dioxide, Propylene Oxide and Cyclohexene Oxide Catalyzed by Rare-earth Ternary Catalyst[J]. Chem. J. Chinese Universities, 2005, 26(12): 2360.

[1]	WU Yu, LI Xuan, YANG Hengpan, HE Chuanxin. Construction of Cobalt Single Atoms via Double-confinement Strategy for High-performance Electrocatalytic Reduction of Carbon Dioxide [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220343.
[2]	CUI Wei, ZHAO Deyin, BAI Wenxuan, ZHANG Xiaodong, YU Jiang. CO₂ Absorption in Composite of Aprotic Solvent and Iron-based Ionic Liquid [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220120.
[3]	HE Hongrui, XIA Wensheng, ZHANG Qinghong, WAN Huilin. Density-functional Theoretical Study on the Interaction of Indium Oxyhydroxide Clusters with Carbon Dioxide and Methane [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220196.
[4]	HUANG Xiaoshun, MA Haiying, LIU Shujuan, WANG Bin, WANG Hongli, QIAN Bo, CUI Xinjiang, SHI Feng. Recent Advances on Indirect Conversion of Carbon Dioxide to Chemicals [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220222.
[5]	SONG Dewen, WANG Mingwang, WANG Yani, JIAO Zhenmei, NING Hui, WU Mingbo. Progress of CO₂ Electroreduction to Oxalic Acid [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220248.
[6]	ZHAO Runyao, JI Guipeng, LIU Zhimin. Efficient Electrocatalytic CO₂ Reduction over Pyrrole Nitrogen-coordinated Single-atom Copper Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220272.
[7]	GUO Zhiqiang, YANG Boru, XI Chanjuan. Recent Advances in Reductive Functionalization of Carbon Dioxide with Borohydride Reagents [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220199.
[8]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[9]	QIU Liqi, YAO Xiangyang, HE Liangnian. Visible-light-driven Selective Reduction of Carbon Dioxide Catalyzed by Earth-abundant Metalloporphyrin Complexes [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220064.
[10]	ZHANG Zhen, DENG Yu, ZHANG Qinfang, YU Dagang. Visible Light-driven Carboxylation with CO₂ [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220255.
[11]	WANG Lijun, LI Xin, HONG Song, ZHAN Xinyu, WANG Di, HAO Leiduan, SUN Zhenyu. Efficient Electrocatalytic CO₂ Reduction to CO by Tuning CdO-Carbon Black Interface [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220317.
[12]	SONG Yingying, HUANG Lin, LI Qingsen, CHEN Limiao. Preparation of CuO/BiVO₄ Photocatalyst and Research on Carbon Dioxide Reduction [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220126.
[13]	TAO Yu, OU Honghui, LEI Yongpeng, XIONG Yu. Research Progress of Single-atom Catalysts in Photocatalytic Reduction of Carbon Dioxide [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220143.
[14]	ZHONG Shengguang, XIA Wensheng, ZHANG Qinghong, WAN Huilin. Theoretical Study on Direct Conversion of CH₄ and CO₂ into Acetic Acid over MCu₂O_x（M = Cu²⁺， Ce⁴⁺， Zr⁴⁺） Clusters [J]. Chem. J. Chinese Universities, 2021, 42(9): 2878.
[15]	YANG Tao, YAO Huiying, LI Qing, HAO Wei, CHI Lifeng, ZHU Jia. Density Functional Theoretical Studies on the Promising Electrocatalyst of M-BHT（M=Co or Cu） for CO₂ Reduction to CH₄ [J]. Chem. J. Chinese Universities, 2021, 42(4): 1268.

Terpolymerization of Carbon Dioxide, Propylene Oxide and Cyclohexene Oxide Catalyzed by Rare-earth Ternary Catalyst

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments