Effect of Cu2+ on the Optical Properties of Poly(3-hexylthiophene) in Different Phases

Abstract

Abstract:

The interactions between Cu²⁺ and poly(3-hexylthiophene)(P3HT) in three different phases(dilute solution, dispersive solution and film), were investigated with UV-Vis absorption spectroscopy and photoluminescence spectroscopy. Our results indicate that the phase state of P3HT has a remarkable influence on the interactions. In the dilute THF solution, there is almost no chemical interaction between Cu²⁺ and P3HT due to the high degrees of solvation of both them, while in the dispersive solution, the Cu²⁺ partially enters into the dispersive particles and leads to weak oxidative doping of P3HT. In P3HT films, the presence of Cu²⁺ makes the conjugation length of P3HT become shorter and causes a blue-shift in the absorption spectroscopy.

Key words: Poly(3-hexylthiophene), Copper ion, Optical property

TrendMD:

ZHU Jun, PENG Rui-Xiang, WANG Ming-Tai. Effect of Cu²⁺ on the Optical Properties of Poly(3-hexylthiophene) in Different Phases[J]. Chem. J. Chinese Universities, 2009, 30(4): 792.

References

Forrest S. R.. Nature
[J], 2004, 428(6986): 911—918
Sirringhaus H., Tessler N., Friend R. H.. Science
[J], 1998, 280(5370): 1741—1744
Andersson M. R., Thomas O., Mammo W., et al.. J. Mater. Chem.
[J], 1999, 9(9): 1933—1940
McQuade D. T., Pullen A. E., Swager T. M.. Chem. Rev.
[J], 2000, 100(7): 2537—2574
Li Y. F., Zou Y. P.. Adv. Mater.
[J] 2008, 20(15): 2952—2958
Wang W. L., Wu H. B., Yang C. Y., et al.. Appl. Phys. Lett.
[J], 2008, 90(18): 183512-1—3
Yang X. N., Loos J., Veenstra S. C., et al.. Nano. Lett.
[J], 2005, 5(4): 579—583
HAO Yan-Zhong(郝彦忠), WANG Wei(王伟). Chem. J. Chinese Universities(高等学校化学学报)
[J], 2007, 28(3): 514—517
McCullough R. D., Tristram-Nagle S., Williams S. P., et al.. J. Am. Chem. Soc.
[J], 1993, 115(11): 4910—4911
Osaka I., Mccullough R. D.. Acc. Chem. Res.
[J], 2008, 41(9): 1202—1214
Abdou M. S. A., Lu X., Xie Z. W., et al.. Chem. Mater.
[J], 1995, 7(4): 631—641
Gourier D., Tourillon G.. J. Phys. Chem.
[J], 1986, 90(22): 5561—5565
Goto H., Okamoto Y., Yashima E.. Chem. Eur. J.
[J], 2002, 8(17): 4027—4036
Goto H., Yashima E.. J. Am. Chem. Soc.
[J], 2002, 142(27): 7943—7949
McCullough R. D., Williams S. P.. Chem. Mater.
[J], 1995, 7(11): 2001—2003
Loewe R. S., Khersonsky S. M., McCullough R. D.. Adv. Mater.
[J], 1999, 11(3): 250—258
Skotheim T. A., Elsenbaumer R. L., Reynolds J. R.. Handbook of Conducting Polymers, 2nd Ed.
[M], New York: Marcell Dekker, 1998: 225—228
Yamamoto T., Komarudin D., Arai M., et al.. J. Am. Chem. Soc.
[J], 1998, 120(9): 2047—2058
Brown P. J., Thomas D. S., Kohler A., et al.. Phys. Rev. B.
[J], 2003, 67(6): 064203-1—16
Lebedev M. Y., Lauritzen M. V., Curzon A. E., et al.. Chem. Mater.
[J], 1998, 10(1): 156—163
Singh R. K., Kumar J., Singh R., et al.. New J. Phys.
[J], 2006, 8: 112-1—21
Yamada K., Tanaka H., Yagishita S., et al.. Inorg. Chem.
[J], 2006, 45(11): 4322—4324
Cornil J., Santos D. A., Crispin X., et al.. J. Am. Chem. Soc.
[J], 1998, 120(6): 1289—1299
Spano F. C.. J. Chem. Phys.
[J], 2005, 122(23): 234701-1—15

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Effect of Cu²⁺ on the Optical Properties of Poly(3-hexylthiophene) in Different Phases

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