Synthesis, Characterization and Properties of Iron(Ⅲ) meso-Tetrakis(4-alkoxyphenyl)porphyrin Chloride

Chem. J. Chinese Universities

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Synthesis, Characterization and Properties of Iron(Ⅲ) meso-Tetrakis(4-alkoxyphenyl)porphyrin Chloride

XU Yong-Jun¹, GU Zheng^2,3, ZHAO Hong-Bin^1,2*, WANG Li-Shen¹, NING Man-Xia¹, QIU Shi-Jun²

1. Department of Chemical Biotechnology, Dongguan University of Technology, Dongguan 523808, China;
2. College of Chemistry, Xiangtan University, Xiangtan 411105, China;
3. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

Received:2008-02-02 Revised:1900-01-01 Online:2008-10-10 Published:2008-10-10
Contact: ZHAO Hong-Bin

Abstract

Abstract: A series of iron(Ⅲ) meso-tetrakis(4-alkoxyphenyl)porphyrin chloride were synthesized, seven of which were new compounds. Molecular structures of all synthesized compounds were confirmed by IR, UV, ¹H NMR, MS spectra and elemental analysis. Differential scanning calorimetry and polarizing microscope(PM) were used to probe the liquid crystal properties of the serial compounds. Eight compounds were found to exhibit liquid crystal(LC) properties, which behaved the single-change liquid crystals or the enantiotropic liquid crystals. Under PM, the LC texture was observed and filamentary optical one was displayed. The effects of alkoxy chains, metal ions of complexes and molecular space structure on liquid crystal properties were investigated. Verifying the (μ-oxy)bis[meso-tetrakis(4-alkoxyphenyl)porphyrin iron(Ⅲ)] and iron(Ⅲ) meso-tetrakis(4-alkoxyphenyl) porphyrin chloride could convert mutually in the adverse reaction by fluorescence spectrum.

Key words: Iron porphyrin complex, Liquid crystal property, Fluorescence spectrum

CLC Number:

O614

TrendMD:

XU Yong-Jun¹, GU Zheng^2,3, ZHAO Hong-Bin^1,2*, WANG Li-Shen¹, NING Man-Xia¹, QIU Shi-Jun². Synthesis, Characterization and Properties of Iron(Ⅲ) meso-Tetrakis(4-alkoxyphenyl)porphyrin Chloride[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Characterization and Properties of Iron(Ⅲ) meso-Tetrakis(4-alkoxyphenyl)porphyrin Chloride

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