Synthesis, Characterization and Catalytic Activities of Mesoporous Titanosilicate Material with MFI Framework

Chem. J. Chinese Universities

• 研究论文 • Previous Articles Next Articles

Synthesis, Characterization and Catalytic Activities of Mesoporous Titanosilicate Material with MFI Framework

ZOU Yong-Cun^*, WEI Shi-Gang, QU Xue-Jian

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Received:2008-04-23 Revised:1900-01-01 Online:2008-10-10 Published:2008-10-10
Contact: ZOU Yong-Cun

Abstract

Abstract: Mesoporous titanosilicates with MFI structure were prepared by assembling from TS-1 nanocluster with mesoporous carbon as the hard-templates. The characterization results show that the sample is of 2D hexagonal ordered mesostructure with MFI micro-structure in the framework. Additionally, SEM images confirm the existence of macropores. Such titanosilicate shows a high catalytic activity in epoxidation of cyclohexene. This mesoporous TS-1 sample would have widely potential applications in industry because of the combining advantages of microporous TS-1(high catalytic activities) and mesoporous materials(mesoporous channels).

Key words: Titanosilicate, Mesoporous material, TS-1, Catalytic oxidation

CLC Number:

TrendMD:

ZOU Yong-Cun^*, WEI Shi-Gang, QU Xue-Jian. Synthesis, Characterization and Catalytic Activities of Mesoporous Titanosilicate Material with MFI Framework[J]. Chem. J. Chinese Universities, doi: .

[1]	GUO Cheng, ZHANG Wei, TANG Yun. Ordered Mesoporous Materials： History， Progress and Perspective [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220167.
[2]	GONG Yanxi, WANG Jianbing, CHAI Buyu, HAN Yuanchun, MA Yunfei, JIA Chaomin. Preparation of Potassium Doped g-C₃N₄ Thin Film Photoanode and Its Application in Photoelectrocatalytic Oxidation of Diclofenac Sodium in Water [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220005.
[3]	WANG Mingzhi, ZHENG Yanping, WENG Weizheng. Catalytic Methane Combustion over CeO₂ Supported PdO and Ce_1‒_x Pd _x O_2‒_δ Species [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210816.
[4]	CHEN Wangsong, LUO Lan, LIU Yuguang, ZHOU Hua, KONG Xianggui, LI Zhenhua, DUAN Haohong. Recent Progress in Photoelectrochemical H₂ Production Coupled with Biomass-derived Alcohol/aldehyde Oxidation [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210683.
[5]	ZHANG Xu, QUE Jiaqian, HOU Yuexin, LYU Jiamin, LIU Zhan, LEI Kunhao, YU Shen, LI Xiaoyun, CHEN Lihua, SU Baolian. Hierarchical Mesoporous-microporous TS-1 Single Crystal Catalysts for Epoxidation of Allyl Chloride [J]. Chem. J. Chinese Universities, 2021, 42(8): 2529.
[6]	SHE Peihong, XU Wenzhou, GUAN Buyuan. Synthesis and Application of Silica/carbon-based Large-pore Mesoporous Nanomaterials [J]. Chem. J. Chinese Universities, 2021, 42(3): 671.
[7]	JIN Shaoqing, SUN Hongmin, YANG Weimin. Applications of Zeolite Catalysts in Chemical Industry [J]. Chem. J. Chinese Universities, 2021, 42(1): 217.
[8]	LI Xiao,XING Lisha,ZHAO Wanjun,WANG Yongzhao,ZHAO Yongxiang. Preparation and Characterization of Pd-Cu/hydroxyapatite Catalyst and Its Catalytic Performance for Room-temperature CO Oxidation in Humid Circumstances^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1600.
[9]	SUN Lin, ZHANG Han, DU Yiping. Preparation of Surface Enhanced Raman Scattering Substrates Based on SBA-15 Material and the Detection of Enrofloxacin in Chicken and Chicken Feed^† [J]. Chem. J. Chinese Universities, 2018, 39(3): 455.
[10]	JIANG Yilan, YUAN Long, WANG Xiyang, HUANG Keke, FENG Shouhua. Effect of Defect Tuning on the Catalytic Behavior of Perovskite Structure Lanthanum Manganite^† [J]. Chem. J. Chinese Universities, 2018, 39(3): 416.
[11]	SUN Bing,JIANG Shang,WANG Runwei,NI Ling,QIU Shilun,ZHANG Zongtao. Preparation and Application of High Performance Lithium Titanate/reduced Graphene Oxide Nanocomposites for Lithium Batteries^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2767.
[12]	SUN Kaifang, CAI Cheng, HOU Zongsheng, WANG Ying, REN Qizhi. Synthesis, Characterization and Catalytic Properties of Series of Water-soluble Sulfonated Porphyrins^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1117.
[13]	ZHANG Yuanyuan, LI Fenpei, LIU Xiangqing, CHEN Haiyan, LUO Ying, JING Lihong, LU Jiaxing, ZHANG Guirong. Methanol Electrocatalytic Oxidation on Pt/Poly(o-toluidine) Film/Activated Carbon Doped Graphite Carbon Paste Electrode^† [J]. Chem. J. Chinese Universities, 2017, 38(12): 2320.
[14]	ZHANG Jinshuai, YU Fengli, TAO Renqing, XIE Congxia, YUAN Bing, YU Shitao. Selective Oxidation of Cyclopentene to Glutaraldehyde Catalyzed by Heteropolyphosphatotungstate Ionic Liquids^† [J]. Chem. J. Chinese Universities, 2017, 38(12): 2248.
[15]	MA Yongjun, DING Jing, JIN Zhimei, TIE Zhenzhen, ZHOU Min. Inhibiting Effect of Chloride Ion for the Electro-oxidation Reaction of Four Organic Alcohols on a Chemically Modified Platinum Anode^† [J]. Chem. J. Chinese Universities, 2015, 36(5): 864.

Synthesis, Characterization and Catalytic Activities of Mesoporous Titanosilicate Material with MFI Framework

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments