Synthesis and Characterization of a Second-order Nonlinear Optical Organic/Inorganic Polyimide Hybrid Material

Abstract

Abstract: Asecond order nonlinear optical(NLO) organic/inorganic hybrid polyimide was successfully prepared by sol gel process, and was characterized by FTIRspectroscopy, UV-Vis spectroscopy, SEM, DSCand TGA. The order parameter of the hybrid material after the polarization is 048 and it maintains 90% of the initial value after the treatment for 300 h at 150 ℃. The SEManalysis shows that the surface of the hybrid thin film is very smooth, and cross-linking structure is observed in the cross section. The T_g of the polyimide/inorganic hybrid material(561 K) is higher than that of the corresponding pure polyimide(543 K). The sol gel hybrid thin film also exhibits a good thermal stability, with 5% and 10% weight loss temperatures at 691 and 758 K, respectively.

Key words: Organic/inorganic hybrid material, Polyimide, Second order nonlinear optical material

CLC Number:

O631.2⁺4

TrendMD:

PAN Xiao-Xia, SUI Yu, XU Hong-Jie, YIN Jie, MA Xiao-Dong, ZHU Zi-Kang, WANG Zong-Guang . Synthesis and Characterization of a Second-order Nonlinear Optical Organic/Inorganic Polyimide Hybrid Material[J]. Chem. J. Chinese Universities, 2002, 23(8): 1618.

[1]	QIU Xinsheng, WU Qin, SHI Daxin, ZHANG Yaoyuan, CHEN Kangcheng, LI Hansheng. Preparation and High Temperature Fuel Cell Performance of Ionic Crosslinked Sulfonated Polyimides for Proton Exchange Membranes [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220140.
[2]	ZHAO Junyu, WANG Chunbo, WANG Chengyang, ZHANG Ke, CONG Bing, YANG Lan, ZHAO Xiaogang, CHEN Chunhai. Preparation and Performance of Thermally Conductive Expanded Graphite/Polyetherimide Composites [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210800.
[3]	WANG Shoubai, WU Xiuming, SHU Chen, ZHONG Min, HUANG Wei, YAN Deyue. Gas Separation Performance of Polyimide Homogeneous MembranesContaining tert-Butyl Groups [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220357.
[4]	JIANG Liqi, WEI Ke, WANG Lang, XIAO Houdi, YANG Jiuxiang, HU Zhiyi, LIU Jing, LI Yu, LYU Mingyun, SU Baolian. Electrochromic Property of the WO₃/PANI Core-Shell Inverse Opal Structure Film [J]. Chem. J. Chinese Universities, 2021, 42(9): 2996.
[5]	WANG Shoubai, WU Xiuming, WU Jinming, TANG Yanfeng, SHU Chen, ZHONG Min, HUANG Wei, YAN Deyue. Synthesis and Properties of Soluble Transparent Polyimides Containing tert-Butyl and Isobutyl Groups [J]. Chem. J. Chinese Universities, 2021, 42(9): 2944.
[6]	ZHU Deshuai, ZHAO Jianying, YANG Zhenghui, GUO Haiquan, GAO Lianxun. Graphene Oxide/Polyimide Composites with High Energy Storage Density Based on Multilayer Structure [J]. Chem. J. Chinese Universities, 2021, 42(8): 2694.
[7]	HUANG Congcong, ZHANG Baoqing, LIU Chenyang. Predicting the Glass Transition Temperature of Polyimides： Group Additive Property Method and Assigning the Group Contributions to Unknown Groups [J]. Chem. J. Chinese Universities, 2021, 42(8): 2617.
[8]	WANG Xianwei, KE Hongjun, YUAN Hang, LU Gewu, LI Liying, MENG Xiangsheng, SONG Shulin, WANG Zhen. High Temperature Resistant and Soluble Polyimide Resins and Their Composites [J]. Chem. J. Chinese Universities, 2021, 42(6): 2041.
[9]	WU Tao, FANG Yuting, DONG Jie, ZHAO Xin, ZHANG Qinghua. Synthesis and Properties of Polyimide Resin Containing Acetylene and Benzoxazine Double Crosslinking Moieties [J]. Chem. J. Chinese Universities, 2021, 42(6): 1978.
[10]	XU Xiaozhou, LIU Yi, HE Minhui, MO Song, LAN Bangwei, ZHAI Lei, FAN Lin. Effect of Copolymerization Structure and Molecular Weight on Melt Fluidity and Thermal Properties of Thermoplastic Polyimide Resins [J]. Chem. J. Chinese Universities, 2021, 42(3): 919.
[11]	BAI Lan, ZHAI Lei, WANG Changou, HE Minhui, MO Song, FAN Lin. Thermal Expansion Behavior of Amide-containing Polyimide Films with Ultralow Thermal Expansion Coefficient ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 795.
[12]	YIN Wenjing, LIU Xiao, QIAN Huidong, ZOU Zhiqing. Preparation and Oxygen Reduction Performance of Fe, N co-Doped arbon Nanoplate with High Density of Active Sites^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1480.
[13]	LIU Tao,LI Wenjing,ZHANG Enshuang,ZHONG Jinyang,ZHANG Fan,LIU Yuanyuan,ZHAO Yingmin. Preparation and Properties of Flexible Cross-linked Polyimide Aerogels [J]. Chem. J. Chinese Universities, 2019, 40(2): 403.
[14]	LIU Yi, XU Xiaozhou, MO Song, ZHAI Lei, HE Minhui, FAN Lin. Thermal Stability of Polyimide Resins Containing Siloxane Structure and Their High Temperature Structural Evolution [J]. Chem. J. Chinese Universities, 2019, 40(1): 187.
[15]	WANG Peng, WU Xian, ZHANG Hanyu, YOU Kaiyuan, LIU Zhenchao, LIU Baijun. Preparation of the Blend Membranes Based on Sulfonated Polyetheretherketoneketone and Amine-terminated Hyperbranched Polyimide^† [J]. Chem. J. Chinese Universities, 2018, 39(3): 405.

Synthesis and Characterization of a Second-order Nonlinear Optical Organic/Inorganic Polyimide Hybrid Material

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments