Voltammetric Study on Nickel(Ⅱ) Complex of meso-Tetra-(4-N-methylpyridyl) porphyrin in Aqueous Solution

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (8): 1136.

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Voltammetric Study on Nickel(Ⅱ) Complex of meso-Tetra-(4-N-methylpyridyl) porphyrin in Aqueous Solution

HOU Jian-Min, GAO Xiao-Xia

Department of Chemistry, Peking University, Beijing, 100871

Received:1993-09-29 Revised:1994-03-30 Online:1994-08-24 Published:1994-08-24

Abstract

Abstract: The electrochemical behavior of nickel(Ⅱ)complex of meso-tetra(4-N-methylpyridyl)porphyrin(TMPyP):in aqueous solution has been investigated by cyclic voltammetric, stripping voltammetric and chronocoulometric techniques. Areductive complex wave exhibited at -1.0 V(vs. Ag/AgCl)in ammoniacal buffer solution(pH=9.0) may be attributed to the six-electron transfer reduction of both Ni(Ⅱ) and TMPyPin the complex.It has heen demonstrated that Ni(Ⅱ)in the complex is reduced to Ni(0).It was observed that no significant influence upon the cyclic voltammograms of NiTMPyPby the dissolved oxygen as compared with Mn²⁺, Fe²⁺, Co²⁺ metalloporphrins.

Key words: Water-soluble nickel-porphyrin, Effect of dissolved oxygen, Voltammetry

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HOU Jian-Min, GAO Xiao-Xia. Voltammetric Study on Nickel(Ⅱ) Complex of meso-Tetra-(4-N-methylpyridyl) porphyrin in Aqueous Solution[J]. Chem. J. Chinese Universities, 1994, 15(8): 1136.

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Voltammetric Study on Nickel(Ⅱ) Complex of meso-Tetra-(4-N-methylpyridyl) porphyrin in Aqueous Solution

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