Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (3): 447.doi: 10.7503/cjcu20170339
• Analytical Chemistry • Previous Articles Next Articles
GAO Chengyao1,2,3, TONG Jianhua1, BIAN Chao1, SUN Jizhou1, LI Yang1, WANG Jinfen4, GONG Shun1, HUI Yun1, XIA Shanhong1,*()
Received:
2017-05-31
Online:
2018-03-10
Published:
2018-01-23
Contact:
XIA Shanhong
E-mail:shxia@mail.ie.ac.cn
Supported by:
CLC Number:
TrendMD:
GAO Chengyao, TONG Jianhua, BIAN Chao, SUN Jizhou, LI Yang, WANG Jinfen, GONG Shun, HUI Yun, XIA Shanhong. Electroanalytical Sensing of Trace Cd(Ⅱ) Using in-situ Bismuth Modified Boron Doped Diamond Electrode†[J]. Chem. J. Chinese Universities, 2018, 39(3): 447.
Fig.11 Stripping voltammograms for various concentrations of Cd(Ⅱ) in 0.1 mol/L acetic acid(A) and calibration curves for analysis of 1—10 μg/L of Cd(Ⅱ)(B)
Forgein ion | Ratio of forgein ions/analyte | Peak current decrease ratio(%) | Forgein ion | Ratio of forgein ions/analyte | Peak current decrease ratio(%) |
---|---|---|---|---|---|
K+ | 100∶1 | -0.3 | Hg2+ | 5∶1 | 4.2 |
Na+ | 100∶1 | -0.1 | Cr6+ | 5∶1 | 3.5 |
Ca2+ | 100∶1 | 2.1 | Zn2+ | 2∶1 | 2.3 |
Mg2+ | 100∶1 | -0.8 | Zn2+ | 3∶1 | 4.1 |
HC | 100∶1 | 0.5 | Pb2+ | 2∶1 | 4.3 |
N | 100∶1 | -0.2 | Pb2+ | 3∶1 | 11.0 |
Cl- | 100∶1 | 0.9 | Cu2+ | 1∶1 | 21.6 |
S | 100∶1 | -0.5 | Cu2+ | 2∶1 | 72.4 |
As3+ | 5∶1 | 3.6 | Cu2+ | 3∶1 | 88.5 |
Table 1 Interference study of Cd determination
Forgein ion | Ratio of forgein ions/analyte | Peak current decrease ratio(%) | Forgein ion | Ratio of forgein ions/analyte | Peak current decrease ratio(%) |
---|---|---|---|---|---|
K+ | 100∶1 | -0.3 | Hg2+ | 5∶1 | 4.2 |
Na+ | 100∶1 | -0.1 | Cr6+ | 5∶1 | 3.5 |
Ca2+ | 100∶1 | 2.1 | Zn2+ | 2∶1 | 2.3 |
Mg2+ | 100∶1 | -0.8 | Zn2+ | 3∶1 | 4.1 |
HC | 100∶1 | 0.5 | Pb2+ | 2∶1 | 4.3 |
N | 100∶1 | -0.2 | Pb2+ | 3∶1 | 11.0 |
Cl- | 100∶1 | 0.9 | Cu2+ | 1∶1 | 21.6 |
S | 100∶1 | -0.5 | Cu2+ | 2∶1 | 72.4 |
As3+ | 5∶1 | 3.6 | Cu2+ | 3∶1 | 88.5 |
Fig.12 Stripping voltammograms of different concentrations of Cu(Ⅱ) added to a solution of 50 μg/L Cd(Ⅱ)a. 50 μg/L Cd2+; b. 50 μg/L Cd2++50 μg/L Cu2+; c. 50 μg/L Cd2++100 μg/L Cu2+; d. 50 μg/L Cd2++150 μg/L Cu2+; e. 50 μg/L Cd2++150 μg/L Cu2++100 μmol/L Fe(CN.
Sample | Added/(μg·L-1) | Found/(μg·L-1) | Recovery(%) |
---|---|---|---|
Tap water | Not found | ||
10.0 | 10.2 | 102 | |
20.0 | 20.3 | 101 | |
30.0 | 29.5 | 98 | |
Pond water 1 | Not found | ||
10.0 | 10.7 | 107 | |
20.0 | 19.3 | 97 | |
30.0 | 29.5 | 98 | |
Pond water 2 | Not found | ||
10.0 | 9.6 | 96 | |
20.0 | 20.5 | 103 | |
30.0 | 31.2 | 104 |
Table 2 Analysis results of Cd ion in real water samples
Sample | Added/(μg·L-1) | Found/(μg·L-1) | Recovery(%) |
---|---|---|---|
Tap water | Not found | ||
10.0 | 10.2 | 102 | |
20.0 | 20.3 | 101 | |
30.0 | 29.5 | 98 | |
Pond water 1 | Not found | ||
10.0 | 10.7 | 107 | |
20.0 | 19.3 | 97 | |
30.0 | 29.5 | 98 | |
Pond water 2 | Not found | ||
10.0 | 9.6 | 96 | |
20.0 | 20.5 | 103 | |
30.0 | 31.2 | 104 |
[1] | Guo D. W., Zhao X. W., Jia Q., Zhou W. H., Chem. Res. Chinese Universities, 2012, 28(1), 26—30 |
[2] | Zhang J. Y., Fang J. L., Duan X. C., Spectrochim. Acta B, 2016, 122, 52—55 |
[3] | Sabermahani F., Askari R., Hosseinifard S. J., Saeidi M., Scientia Iranica, 2014, 21(6), 2012—2020 |
[4] | Sugihara Y., Hayakawa S., Namatame H., Hirokawa T., Bunseki Kagaku, 2011, 60(8), 613—618 |
[5] | Wen X. D., Deng Q. W., Guo J., Yang S. C., Spectrochim. Acta A, 2011, 79(3), 508—512 |
[6] | Ge F., Cao R. G., Zhu B., Li J. J., Xu D. S., Acta Phys-Chim. Sin., 2010, 26(7), 1779—1783 |
(戈芳, 曹瑞国, 朱斌, 李经建, 徐东升.物理化学学报,2010, 26(7), 1779—1783) | |
[7] | Wang Y. G., Lin W. R., Chem. J. Chinese Universities, 1982, 3(9), 31—36 |
(王耀光, 林文如.高等学校化学学报,1982, 3(9), 31—36) | |
[8] | Farooqi M. O., Taimoor A. A., Al-Shahrani S., Baleanu D., Rather S. U., Revista De Chimie, 2015, 66(4), 499—502 |
[9] | Bi Z. S., Salaun P., van den Berg C. M. G., Electroanalysis, 2013, 25(2), 357—366 |
[10] | Wang J., Lu J. M., Hocevar S. B., Farias P. A. M., Ogorevc B., Anal. Chem., 2000, 72(14), 3218—3222 |
[11] | Wang J., Electroanal., 2005, 17(15/16), 1341—1346 |
[12] | Lee S., Park S. K., Choi E., Piao Y., J. Electroanal. Chem., 2016, 766, 120—127 |
[13] | Wu M., Li H., Wang X., Wang Q. J., He P. G., Fang Y. Z., Chinese J. Anal. Chem., 2015, 43(4), 553—557 |
(吴敏, 李辉, 汪雪, 王清江, 何品刚, 方禹之, 分析化学, 2015, 43(4), 553—557) | |
[14] | Gao C. Y., Chang M., Acta Phys-Chim. Sin., 2008, 24(11), 1988—1994 |
(高成耀, 常明.物理化学学报,2008, 24(11), 1988—1994) | |
[15] | Shin D., Tryk D. A., Fujishima A., Merkoci A., Wang J., Electroanal., 2005, 17(4), 305—311 |
[16] | Fierro S., Watanabe T., Akai K., Yamanuki M., Einaga Y., J. Electrochem. Soc., 2011, 158(11), F173—F178 |
[17] | Argun A. A., Banks A. M., Merlen G., Tempelman L. A., Becker M. F., Schuelke T., Dweik B. M., Anal. Chim. Acta, 2013, 773, 45—51 |
[18] | Culkova E., Svorc L., Tomcik P., Durdiak J., Rievaj M., Bustin D., Breseher R., Lokaj J., Pol. J. Environ. Stud., 2013, 22(5), 1317—1323 |
[19] | Arantes T. M., Sardinha A., Baldan M. R., Cristovan F. H., Ferreira N. G., Talanta, 2014, 128, 132—140 |
[20] | Fierro S., Watanabe T., Akai K., Einaga Y., Electrochim. Acta, 2012, 82, 9—11 |
[21] | Nagaoka Y., Ivandini T. A., Yamada D., Fujita S., Yamanuki M., Einaga Y., Chem. Lett., 2010, 39(10), 1055—1057 |
[22] | Sonthalia P., McGaw E., Show Y., Swain G. M., Anal. Chim. Acta, 2004, 522(1), 35—44 |
[23] | Manivannan A., Ramakrishnan L., Seehra M. S., Granite E., Butler J. E., Tryk D. A., Fujishima A., J. Electroanal. Chem., 2005, 577(2), 287—293 |
[24] | Saterlay A. J., Foord J. S., Compton R. G., Analyst, 1999, 124(12), 1791—1796 |
[25] | Neodo S., Nie M., Wharton J. A., Stokes K. R., Electrochim. Acta, 2013, 88, 718—724 |
[26] | Honorio G. G., Azevedo G. C., Matos M. A. C., de Oliveira M. A. L., Matos R. C., Food Control, 2014, 36(1), 42—48 |
[27] | Crowley K., Cassidy J., Electroanal., 2002, 14(15/16), 1077—1082 |
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