The Study of Weak Metal-Metal Bond in Mo4(μ3-O)2O4·Cl2(O2CC6H5)6 and Mo4(μ3-O)2O4Cl2(O2CC6H4CH3)6·2C6H5ClClusters

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (2): 164.

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The Study of Weak Metal-Metal Bond in Mo₄(μ₃-O)₂O₄·Cl₂(O₂CC₆H₅)₆ and Mo₄(μ₃-O)₂O₄Cl₂(O₂CC₆H₄CH₃)₆·2C₆H₅ClClusters

Jiang Yueshun¹, Chai Xjangdong¹, Zhang Hengbin¹, Shun Chun ting¹, Li Tiejin¹, Jiang Yian²

1. Department of Chemistry, Jilin University, Changchun;
2. Chemistry Engineering Collage, Dalian Institute of Science ant Technology, Dalian

Received:1988-04-11 Online:1990-02-24 Published:1990-02-24

Abstract

Abstract: The UVspectra and cyclic voltammetry property of the two clusters, Mo₄(μs-O)₂O₄Cl2(O₂CC₆H₅)₆ and Mo₄(μ3-O)₂O₄Cl2(O₂CC₆H₄CH₃)₆ · 2C₆H₅Cl, desolved in N, N-dimetylformamide and the SPY (Surface Photovoltage) spectra, Photoacoustic spectra of this two solid state samples are measured. We discuss the properties of the weak metal-metal bond of the Mo2(V) structure unit and assign symmetry properties of Mo-Mo frontier orbits.

Key words: Molybdenum clusters, Metal-Metal bond, Electron spectra, Cyclic voltammetry

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Jiang Yueshun, Chai Xjangdong, Zhang Hengbin, Shun Chun ting, Li Tiejin, Jiang Yian. The Study of Weak Metal-Metal Bond in Mo₄(μ₃-O)₂O₄·Cl₂(O₂CC₆H₅)₆ and Mo₄(μ₃-O)₂O₄Cl₂(O₂CC₆H₄CH₃)₆·2C₆H₅ClClusters[J]. Chem. J. Chinese Universities, 1990, 11(2): 164.

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The Study of Weak Metal-Metal Bond in Mo₄(μ₃-O)₂O₄·Cl₂(O₂CC₆H₅)₆ and Mo₄(μ₃-O)₂O₄Cl₂(O₂CC₆H₄CH₃)₆·2C₆H₅ClClusters

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