Chem. J. Chinese Universities ›› 2022, Vol. 43 ›› Issue (7): 20220223.doi: 10.7503/cjcu20220223

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Applications of Metal-organic Framework-based Material in Carbon Dioxide Photocatalytic Conversion

ZHAO Yingzhe1,2, ZHANG Jianling1,2()   

  1. 1.Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China
    2.School of Chemical Sciences,University of Chinese Academy of Sciences,Beijing 100049,China
  • Received:2022-04-09 Online:2022-07-10 Published:2022-06-05
  • Contact: ZHANG Jianling E-mail:zhangjl@iccas.ac.cn
  • Supported by:
    the National Natural Science Foundation of China(22033009)

Abstract:

Converting carbon dioxide(CO2) into fuels or high-additional-valued chemicals is an efficient route to decrease atmospheric CO2 concentration and mitigate green-house effect. Particularly, the photocatalytic CO2 conversion is of importance due to its mild reaction condition and low energy consumption. Metal-organic framework-based(MOF-based) materials are a kind of efficient catalyst for CO2 photocatalytic conversion owing to their unique features such as large specific surface area, good photoelectric properties and various tunability. In this article, the applications of MOF-based materials in CO2 photocatalytic reduction, cycloaddition and carboxylation in recent two years were reviewed. The advantages, limitations and future development of MOF-based materials for photocatalytic CO2 conversion reactions were discussed.

Key words: Metal-organic framework, CO2 conversion, Photocatalysis, Structure-activity relationship

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