Syntheses and Optical Properties of Two Novel Terpyridine Derivatives†

doi:10.7503/cjcu20131226

Abstract

Abstract:

Two novel D-π-A type terpyridine derivatives with two-photon properties were synthesized using 2,2'∶6',2″-terpyridine as the acceptor(A) and other functional groups as the donor(D). For the two D-π-A type terpyridine derivatives, their linear absorption, single- and two-photon properties were measured. These results show that the target compounds have good fluorescence with the fluorescence quantum yield(Ф)up to 0.45 and the maximal two-photon absorption cross section(δ₂) up to 406 GM at 830 nm. Theoretical calculations were consistent with the experimental results.

Key words: Terpyridine derivative, Optical property, Single-photon fluorescence, Two-photon fluorescence

CLC Number:

O621.22

TrendMD:

GAO Yuanhao, PAN Ruilong, TIAN Yupeng, LI Jing, ZHENG Zhi. Syntheses and Optical Properties of Two Novel Terpyridine Derivatives^†[J]. Chem. J. Chinese Universities, 2014, 35(7): 1439.

Figures/Tables 5

Scheme 1 Synthetic routes of terpyridine derivatives T1 and T2

Fig.1 UV-Vis absorption spectra of compounds T1(a) and T2(b)

Fig.2 Representation of calculated Kohn-Sham orbitals of T1(A, C) and T2(B, D) molecules (A, B) LUMO: -1.30 eV, -1.20 eV; (C, D) HOMO: -4.72 eV, -5.05 eV.

Fig.3 SPEF spectra of T1(a) and T2(b) compounds in ethanol solvent

Fig.4 TPEF spectrum of T1 in DMF(A) and two-photon absorption(TPA) cross section of T1 in DMF(B) Inset of (A): fluorescence power dependence.

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