In situ Synthesis of Silver Nanoparticles on Fabric Attached with Chitosan†

doi:10.7503/cjcu20130678

Abstract

Abstract:

Cotton and polyester fabrics modified with silver nanoparticles were synthesized in situ through the reaction of absorption and reduction of chitosan which was attached on the surface of respective fibers. The obtained nanosilver fabrics were characterized by scanning electronic microseopy(SEM), energy dispersive X-ray(EDX) microscopysis, X-ray diffraction(XRD) and reflectance spectrum, and the influence of the concentration of silver ion and chitosan solution on the nanosilver fabrics was investigated. The antibacterial performances of the prepared nanosilver fabrics towards E. coil and S. aureus were detected. The results indicated that silver nanoparticles were uniformly formed on the surface of cotton and polyester fabrics attahced with chitosan, without any reductant addition. The crystalline size of the silver nanoparticels was about 5—10 nm. The prepared nanosilver cotton and polyester fabrics exhibited good antibacterial activity and antibacterial durability.

Key words: Nanosilver fabric, In situ synthesis, Chitosan, Antibacterial performance

CLC Number:

O636

TrendMD:

PENG Junjun, ZHANG Xin, WU Yiming, LIU Honglin, RAN Jianhua, LI Ming, YANG Feng. In situ Synthesis of Silver Nanoparticles on Fabric Attached with Chitosan^†[J]. Chem. J. Chinese Universities, 2014, 35(2): 415.

Figures/Tables 8

Fig.1 Diagram of preparation of fabrics modified with silver nanoparticles

Fig.2 Photographs of different fabrics(A) Raw cotton; (B) cotton modified with nanosilver; (C) polyester modified with nanosilver.

Fig.3 SEM images of polyester fiber from polyester cloth modified with nano Ag(A, B) and EDX spectrum(C) of polyester cloth modified with nano Ag in (A)(B) Enlarged of image of (A).

Fig.4 XRD patterns of different textiles modified with Ag nanoparticles as indicateda. Polyester; b. polyester/nano Ag; c. cotton;d. cotton/nano Ag.

Fig.5 Curves of reflectance ratio of different textiles modified with Ag nanoparticles as indicateda. Cotton; b. polyester; c. polyester/nano Ag;d. cotton/nano Ag.

Fig.6 Curves of reflectance ratio of polyester cloth modified with Ag nanoparticles prepared by different concentration of AgNO3 solution as indicatedAll samples treated with 0.2%CS solution.

Fig.7 Curves of reflectance ratio of polyester cloth modified with Ag nanoparticles prepared by 0.05 mmol/L AgNO3 solution with different concentration of chitsoan solution as indicated

Table 1 Comparison of antibacterial efficiency(R) of different fabrics

Sample	R of E. coil(%)	R of S. aureus(%)
0.2%CS-Cotton	0.2	0.1
0.2%CS-Polyester	0.2	0.1
0.2%CS-Cotton+50 mL 0.05 mmol/L AgNO₃	99.9	99.9
0.2%CS-Polyester+50 mL 0.05 mmol/L AgNO₃	99.9	99.9
0.2%CS-Cotton+50 mL 0.05 mmol/L AgNO₃ with 50 washing cycles	97.7	94.4
0.2%CS-Polyester+50 mL 0.05 mmol/L AgNO₃ with 50 washing cycles	90.1	85.8

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