Preparation and Adsorption Properties of Novel Magnetic Tetrabromobisphenol A Molecularly Imprinted Composite Material Based on Graphene Oxide Surface

doi:10.7503/cjcu20120960

Chem. J. Chinese Universities ›› 2013, Vol. 34 ›› Issue (6): 1353.doi: 10.7503/cjcu20120960

• Analytical Chemistry • Previous Articles Next Articles

Preparation and Adsorption Properties of Novel Magnetic Tetrabromobisphenol A Molecularly Imprinted Composite Material Based on Graphene Oxide Surface

RAO Wei^1,2, CAI Rong¹, CHEN Xing¹, LIU Yu-Nan¹, CHEN Hong-Jun¹, ZHANG Zhao-Hui^1,2,3, NIE Li-Hua³

1. Key Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie 427000, China;
2. College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China;
3. State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China

Received:2012-10-25 Online:2013-06-10 Published:2013-01-07

Abstract

Abstract:

A novel magnetic molecularly imprinted polymer(Fe₃O₄@GO@MIP) based on magnetic graphene coated with silicon dioxide layer was synthesized using heated polymerization technique. The MIP was characterized by transmission electron microscopy(TEM), scanning electron microscopy(SEM), Fourier transform infrared spectroscopy(FTIR), thermogravimetric analysis(TGA) and vibrating sample magnetometer(VSM). The results showed that a thermal stability magnetic imprinted layer with the thickness of 55-65 nm was coated steadily on the graphene oxide surface. Adsorption performance of the Fe₃O₄@GO@MIP was investigated combined with magnetic solid phase extraction(M-SPE) and high-performance liquid chromatography(HPLC) technology, and the results indicated the Fe₃O₄@GO@MIP possessed higher selectivity towards tetrabromobisphenol A with the maximum adsorption capacity of 16.33 mg/g. The magnetic molecularly imprinted composite material was applied to separation and enrichment of tetrabromobisphenol A in environmental water samples combined with HPLC technology.

Key words: Molecularly imprinted, Graphene oxide, Tetrabromobisphenol A, Magnetic solid phase extraction

CLC Number:

O652.6

TrendMD:

RAO Wei, CAI Rong, CHEN Xing, LIU Yu-Nan, CHEN Hong-Jun, ZHANG Zhao-Hui, NIE Li-Hua. Preparation and Adsorption Properties of Novel Magnetic Tetrabromobisphenol A Molecularly Imprinted Composite Material Based on Graphene Oxide Surface[J]. Chem. J. Chinese Universities, 2013, 34(6): 1353.

[1]	WENG Meiqi, SHANG Guiming, WANG Jiatai, LI Shenghua, FAN Zhi, LIN Song, GUO Minjie. Template Simulation of Organophosphorus Nerve Agent Molecularly Imprinted Polymers [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220136.
[2]	YANG Junge, GAO Chengqian, LI Boxin, YIN Dezhong. Preparation of High Thermal Conductivity Phase Change Monolithic Materials Based on Pickering Emulsion Stabilized by Surface Modified Graphene Oxide [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210593.
[3]	ZHANG Zhibo, SHANG Han, XU Wenxuan, HAN Guangdong, CUI Jinsheng, YANG Haoran, LI Ruixin, ZHANG Shenghui, XU Huan. Self-Assembly of Graphene Oxide at Poly（3-hydroxybutyrate） Microparticles Toward High-performance Intercalated Nanocomposites [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210566.
[4]	HU Bo, ZHU Haochen. Dielectric Constant of Confined Water in a Bilayer Graphene Oxide Nanosystem [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210614.
[5]	YU Bin, CHEN Xiaoyan, ZHAO Yue, CHEN Weichang, XIAO Xinyan, LIU Haiyang. Graphene Oxide-based Cobalt Porphyrin Composites for Electrocatalytic Hydrogen Evolution Reaction [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210549.
[6]	WANG Xueli, SONG Xiangwei, XIE Yanning, DU Niyang, WANG Zhenxin. Preparation， Characterization of Partially Reduced Graphene Oxide and Its Killing Effect on Human Cervical Cancer Cells [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210595.
[7]	ZHU Deshuai, ZHAO Jianying, YANG Zhenghui, GUO Haiquan, GAO Lianxun. Graphene Oxide/Polyimide Composites with High Energy Storage Density Based on Multilayer Structure [J]. Chem. J. Chinese Universities, 2021, 42(8): 2694.
[8]	LI Peihong, ZHANG Chunling, DAI Xueyan, SUI Yanlong. Progress of Graphene Oxide/Polymer Composite Hydrogel [J]. Chem. J. Chinese Universities, 2021, 42(6): 1694.
[9]	MIAO Weijun, WU Feng, WANG Yong, WANG Zongbao. In⁃situ Study of the Epitaxial Crystallization of PCL/RGO at High Shear Rate [J]. Chem. J. Chinese Universities, 2021, 42(3): 910.
[10]	ZHENG Haijiao, JIANG Liyan, JIA Qiong. Arginine Functionalized Magnetic Nanoparticles and Its Application in Phosphopeptides Enrichment [J]. Chem. J. Chinese Universities, 2021, 42(3): 717.
[11]	HUANG Dongxue, ZHANG Ying, ZENG Ting, ZHANG Yuanyuan, WAN Qijin, YANG Nianjun. Transition Metal Sulfides Hybridized with Reduced Graphene Oxide for High-Performance Supercapacitors [J]. Chem. J. Chinese Universities, 2021, 42(2): 643.
[12]	WANG Bowei, MA Rui, WU Fan, LIU Zhihui, LI Lingfeng, ZHANG Xiao, LIU Dingkun, YANG Nan, LI Meihui, YANG Defeng, SUN Qi. Preparation and Characterization of Graphene Oxide-sodium Alginate-chitosan Composite Scaffold [J]. Chem. J. Chinese Universities, 2020, 41(9): 2099.
[13]	ZHANG Weiguo, FAN Songhua, WANG Hongzhi, YAO Suwei. Synthesis of Self-assembled α-Fe₂O₃/Graphene Hydrogel for Supercapacitors with Promising Electrochemical Properties [J]. Chem. J. Chinese Universities, 2020, 41(8): 1850.
[14]	CHEN Yantian, QIE Hantong, ZHANG Yinjie, ZHOU Caiji, TAN Xiao, LIN Aijun. Synthesis of Reduced Graphene Oxide Supported Zero-valent Iron and Its Treatment of TNT Wastewater [J]. Chem. J. Chinese Universities, 2020, 41(8): 1836.
[15]	ZHANG Xiaofei, WU Lie, LI Shanshan, ZHU Manyu, CHENG Xiaowei, JIANG Xiu’e. Effect of Phase Behavior of Phospholipids on Lipid Membrane Damage Induced by Graphene Oxide ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 661.

Preparation and Adsorption Properties of Novel Magnetic Tetrabromobisphenol A Molecularly Imprinted Composite Material Based on Graphene Oxide Surface

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments