高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (11): 1483.

• 研究论文 •    下一篇

酞菁铜(Ⅱ)衍生物的合成及其成膜性

张引, 陈文启, 沈琪   

  1. 中国科学院长春应用化学研究所, 长春 130022
  • 收稿日期:1992-12-29 修回日期:1993-05-03 出版日期:1993-11-24 发布日期:1993-11-24
  • 通讯作者: 陈文启.
  • 作者简介:张引, 女, 35岁, 讲师
  • 基金资助:

    国家自然科学基金

Synthesis of Copper(Ⅱ) Phthalocyanine Derivatives and Their LB Films

ZHANG Yin, CHEN Wen-Qi, SHEN Qi   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022
  • Received:1992-12-29 Revised:1993-05-03 Online:1993-11-24 Published:1993-11-24

PDF (PC)

被引次数

9

摘要： 合成了四-4-(8-喹啉氧基)酞菁铜(Ⅱ)等6种新型酞菁铜衍生物,通过元素分析、红外光谱、顺磁共振、质谱及核磁共振谱加以确认.紫外可见光谱表明它们在氯仿溶液(10-5mol/L)中主要以单分子形式存在,配合物的氯仿溶液在亚相(水)上的π-A曲线表明,它们均有明显的“气-液-固"变化过程,具有良好的形成LB膜性质.

关键词: 酞菁铜衍生物, 合成, LB膜, &pi, -A曲线

Abstract: In this paper, copper (Ⅱ)-tetra-4-(8-quinoloxy) phthalocyanine (A), 4-(8-quinolyoxy)tris-4-(2,4-di-t-pentyl phenoxy)phthalocyanine(B), tetra-4-(β-naphthoxy)phthalo-cyanine(C); 4-(β-naphthoxy)tris-4-(2, 4-di-t-pentyl phenoxy)phthalocyanine(D), tetrakis-4-[4'-4''-benzyloxy phenyl sulfonyl) phenoxy]phthalocyanine(E) and 4-[4'-4''-benzyloxy phenyl sulfonyl) phenoxy]-tris-4-(2, 4-di-t-penoxy)phthalocyanine(F), were synthesized and characterized by elemental analysis, IR, ESR, MSand 1H NMR.UV-Vis spectra indicate that most of them are monomeric molecules in CHCl3 solution.Surface pressure(π-area (A) isotherms for the six kinds of compounds in CHCl3 solution in subphase (water) at 25℃ showed the existence of the obvious changes in the states of “gas", “liquid" and “solid" phases and six kinds of compounds could form monomolecular layer film.

Key words: Phthalocyanine copper(Ⅱ) derivative, Synthesis, LB film, π-A curve

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