高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (6): 843.

• 论文 • 上一篇    下一篇

对烷氧基苯基苯并卟啉的新法合成及性能研究

王杏乔, 高爽, 曹昌盛, 师同顺, 于连香, 曹锡章   

  1. 吉林大学化学系, 长春 130023
  • 收稿日期:1996-01-08 出版日期:1996-06-24 发布日期:1996-06-24
  • 通讯作者: 王杏乔,女,52岁,副教授.
  • 作者简介:王杏乔,女,52岁,副教授.
  • 基金资助:

    国家自然科学基金

A New Method for Synthesis and Characterization of p-Alkoxyl-phenyl-benzoporphyrin

WANG Xing-Qiao, GAO Shuang, CAO Chang-Sheng, SHI Tong-Shun, YU Lian-Xiang, CAO Xi-Zhang   

  1. Department of Chemistry, Jilin University, Changchun 130023
  • Received:1996-01-08 Online:1996-06-24 Published:1996-06-24

摘要: 采用先接链后合环密闭熔融新方法,合成了5个系列25种对烷氧基苯基苯并卟啉。通过紫外、红外、质谱和元素分析等手段进行了表征。初步研究了10种新型卟啉的性能。

关键词: 对烷氧基苯基苯并卟啉, 合成, 卟啉, 性能

Abstract: Anew sealed-melting method was used to synthesize five series of p-alkoxyl-phenyl benzoporphyrins(25 kinds).Alkoxyl was linked up with zinc benzoyl acetate first, then the resulting chain formed a ring with phthalimide.The structures of 10 ktnds of the porphyrins were characterized by UV-Vis,IR,MSand elementary analysis.Their properties were studied preliminarily.

Key words: p-Alkoxyl-phenyl-benzoporphyrin, Synthesis methods, Property of porphyrin

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