高等学校化学学报 ›› 2010, Vol. 31 ›› Issue (8): 1485.

• 研究快报 • 上一篇    下一篇

有机发光分子在聚苯胺微结构上的选择性吸附

田露1,卜凤泉2, 黄春玉1, 吕男1   

  1. 1. 吉林大学超分子结构与材料国家重点实验室, 长春 130012;
    2. 吉林大学药学院, 长春 130012
  • 收稿日期:2009-10-13 出版日期:2010-08-10 发布日期:2010-08-10
  • 通讯作者: 吕男, 女, 博士, 教授, 博士生导师, 主要从事表面图案化与界面诱导组装的研究. E-mail: luenen@jlu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:  20673109)资助.

Selective Adsorption of Organic Light Emitting Molecule on PANI Microstructure

TIAN Lu1, BU Feng-Quan2, HUANG Chun-Yu1, LÜ Nan1*   

  1. 1. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry,
    2. School of Pharmaceutical Science, Jilin University, Changchun 130012, China
  • Received:2009-10-13 Online:2010-08-10 Published:2010-08-10
  • Contact: Lü Nan. E-mail: luenen@jlu.edu.cn
  • Supported by:

    国家自然科学基金(批准号:  20673109)资助.

摘要: 我们将有机发光分子选择性地吸附在PANI结构上形成有机发光图案, 作为诱导模板聚苯胺的结构可以通过纳米压印和沉积相结合的方法制备. 通过在PANI 结构的空隙处修饰氟代硅烷增大样品表面不同区域的亲疏水差异, 从而诱导有机发光分子的选择性吸附.

关键词: 聚苯胺结构模板, 有机发光分子, 迁移, 有机发光分子结构

Abstract: We developed a method for patterning organic light emitting molecules with polyaniline(PANI) \{microstructure\} as a template. Its microstructure was characterized with atomic force microscopy(AFM). PANI microstructure was treated with O2 plasma at low power and short time to get the hydroxyl groups on the silicon substrate, meanwhile, which can minimize the impact on PANI structure. We modified the \{structure\} with fluoro\|silane reagent through self\|assembly to make substrate bearing different surface energies on \{different\} areas. Finally, we deposited dyes on substrate by evaporation. The results show that the dyes on the \{fluoro\|silane\} monolayer can move toward the PANI structure during storage duration and form the structure of organic light emitting molecules.

Key words: PANI\, template, Organic light emitting molecule, Migration, Organic light emitting molecule structure

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