高等学校化学学报 ›› 2020, Vol. 41 ›› Issue (6): 1179-1193.doi: 10.7503/cjcu20190650

• 庆祝《高等学校化学学报》复刊40周年专栏 • 上一篇    下一篇

基于蒽衍生高迁移率发光材料的研究进展

谢子仪1,4,刘单1,3,张逸寒1,3,刘情情1,3,董焕丽1,3,*(),胡文平1,2   

  1. 1. 中国科学院化学研究所, 有机固体院重点实验室, 北京分子科学国家研究中心, 北京 100190
    2. 天津大学理学院, 天津市分子光电科学重点实验室, 天津大学协同创新中心, 天津 300072
    3. 中国科学院大学, 北京 100049
    4. 湘潭大学化学学院, 湘潭 411105
  • 收稿日期:2019-12-11 出版日期:2020-06-10 发布日期:2020-02-17
  • 通讯作者: 董焕丽 E-mail:dhl522@iccas.ac.cn
  • 基金资助:
    国家重点研发计划“纳米科技”专项(2017YFA0204503);国家重点研发计划“战略性先进电子材料”专项(2016YFB0401100);国家自然科学基金(51725304);国家自然科学基金(51733004);国家自然科学基金(61890943);国家自然科学基金(91833306);北京分子科学国家研究中心项目(BNLMS-CXXM-202012);中国科学院青年创新促进会项目

Recent Advances on High Mobility Emissive Anthracene-derived Organic Semiconductors

XIE Ziyi1,4,LIU Dan1,3,ZHANG Yihan1,3,LIU Qingqing1,3,DONG Huanli1,3,*(),HU Wenping1,2   

  1. 1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    2. Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Collaborative Innovation Center of Chemical Science and Engineering, School of Sciences, Tianjin University Tianjin, 300072, China
    3. University of Chinese Academy of Sciences, Beijing 100049, China
    4. College of Chemistry, Xiangtan University, Xiangtan 411105, China
  • Received:2019-12-11 Online:2020-06-10 Published:2020-02-17
  • Contact: Huanli DONG E-mail:dhl522@iccas.ac.cn
  • Supported by:
    † National Key Research and Development Project-Nanotechnology Funding, China(2017YFA0204503);National Key Research and Development Project-Strategic Advanced Electronic Materials Funding, China(2016YFB0401100);National Natural Science Foundation of China(51725304);National Natural Science Foundation of China(51733004);National Natural Science Foundation of China(61890943);National Natural Science Foundation of China(91833306);Beijing National Laboratory for Molecular Sciences, China(BNLMS-CXXM-202012);Youth Innovation Promotion Association of the Chinese Academy of Sciences

摘要:

高迁移率发光有机半导体材料是实现有机发光场效应晶体管(OLETs)的重要材料, 但其设计合成面临巨大挑战. 本文综合评述了近年来高迁移率发光材料, 特别是基于蒽的高迁移率发光材料的研究进展, 重点介绍了目前报道的20余种基于蒽的高迁移率发光有机半导体材料, 包括分子的设计策略、 相关的光电性能及其在OLETs器件方面的应用研究, 以便为进一步的相关研究提供有意义的指导和借鉴. 本文还对该领域未来发展的挑战、 发展方向及机遇进行了简单评述.

关键词: 蒽衍生物, 高迁移率, 强发光, 有机发光场效应晶体管

Abstract:

High mobility emissive organic semiconductors are the important core materials for the realization of organic light-emitting transistors(OLETs). However, it remains a long-standing challenge for developing high mobility emissive organic semiconductors because of the different molecular design requirements as well as their molecular packing in solid state. Recently, significant advance has been achieved in the development of high mobility emissive organic semiconductors, especially for the anthracene-derived high mobility emissive materials, which would lead to the rapid development of this field. In this article, we first give a brief introduction for the significant progress in the whole field, and then focus on special development of high mobility emissive anthracene-derivatives(more than 20 types) along with their molecular structure design, molecular packing and optoelectronic properties as well as their applications in OLETs. Finally, the challenges, development directions and opportunities are discussed. Hopefully, this review would give a valuable guideline for the further research in this field.

Key words: Anthracene derivative, High mobility, Strong solid luminescence, Organic light-emitting transistor

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