高等学校化学学报

高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (9): 1673.

• 研究简报 • 上一篇    下一篇

新型非致密相磷酸锗锌化合物的合成与表征

李冬生, 朱广山, 李亚丰, 高非非, 李滨松, 裘式纶   

  1. 无机合成与制备化学国家重点实验室, 吉林大学化学学院, 长春 130023
  • 收稿日期:2001-05-17 出版日期:2002-09-24 发布日期:2002-09-24
  • 通讯作者: 裘式纶(1948年出生),男,博士,教授,博士生导师,从事无机合成化学研究.
  • 基金资助:

    国家自然科学基金(批准号:G2000077507)资助

Syntheses and Characterization of Novel Open-framework Zinc Germanate Phosphates

LI Dong-Sheng, ZHU Guang-Shan, LI Ya-Feng, GAO Fei-Fei, LI Bin-Song, QIU Shi-Lun    

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, China
  • Received:2001-05-17 Online:2002-09-24 Published:2002-09-24

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被引次数

2

关键词: 溶剂热合成, 空旷骨架, 磷酸锗锌, 晶体

Abstract: Three open-framework zinc germanophosphates have been synthesized from ethylene glycol systems of Zn(Ac)2·2H2O-H3PO4-R-GeO2-Py-EG, where R stands for an amine and EGfor ethylene glycol. It was found that by selecting proper amines as structure-directing templates during crystallization open-framework zinc germanophosphates were synthesized. The structures of the zinc germanophosphates were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), inductively coupled plasma(ICP) analysis, infrared spectroscopy(IR).

Key words: Solvothermal synthesis, Open-framework, Zinc germanate phosphate, Crystal

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