高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (8): 1186.

• 研究简报 • 上一篇    下一篇

Co(En)3MoO4晶体的水热合成与表征

王仁章1, 李亚丰1, 乔晓光1, 杨国昱1, 邢永恒1, 曾庆新1, 徐吉庆1, 林永华2, 邢燕2, 贾恒庆2   

  1. 1. 吉林大学化学系, 长春 130023;
    2. 长春应用化学研究所, 长春 130022
  • 收稿日期:1998-01-27 出版日期:1999-08-24 发布日期:1999-08-24
  • 通讯作者: 徐吉庆
  • 作者简介:王仁章,男,38岁,博士研究生,副教授,现四平师范学院工作.
  • 基金资助:

    国家自然科学基金(批准号:29671012;29733090)资助课题

Hydrothermal Synthesis and Crystal Structure of Co(En)3MoO4

WANG Ren-Zhang1, LI Ya-Feng1, QIAO Xiao-Guang1, YANG Guo-Yu1, XING Yong-Heng1, ZENG Qing-Xin1, XU Ji-Qing1, LIN Yong-Hua2, XING Yan2, JIA Heng-Qing2   

  1. 1. Department of Chemistry, Jilin University, Changchun 130023, China;
    2. Institute of Applied Chemistry, Chinese Academy of Sciences, Chang chun 130022, China
  • Received:1998-01-27 Online:1999-08-24 Published:1999-08-24

PDF (PC)

关键词: 水热合成法, 晶体, P3C1

Abstract: Co(En)3MoO4 was synthesized by using the method of hydrothermal synthesis and characterized by elemental analysis, IR, ESRand single-crystal X-ray methods. It crystal-lizes in hexagonal space group P3C1 with a=1.5964(2) nm, b=1.5964(2) nm, c=0.9935(2) nm, α=β=90°, γ=120°, Mc=399.18, V=2.1926(6) nm3, Dc=1.814 g/nm3, Z=6, F(000)=1218, R1=0.0703, Rw=0.2207. According to separation of anion which acted on electrostatic potential, the anion and cation ions formed a type of organic and inorganic material.

Key words: Hydrothermal synthesis, Crystal, P3C1

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