高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (12): 1954.

• 研究快报 • 上一篇    下一篇

Mn,Co添加Fe1-xMxSi2烧结体的β相转移和稳定性研究

崔湘浩1, 田元益2, 魏长平3   

  1. 1. 吉林大学化学系, 长春 130023;
    2. 理科大学化学系, 朝鲜, 平壤;
    3. 吉林工学院轻纺系, 长春 130012
  • 收稿日期:1998-08-30 出版日期:1999-12-24 发布日期:1999-12-24
  • 通讯作者: 崔湘浩,男,58岁,副教授.
  • 作者简介:崔湘浩,男,58岁,副教授.
  • 基金资助:

    吉林省科学技术委员会;国际合作资助课题

Studies on the Phase Transformation and Stability of the Sintered Compacts FeSi2Doped with Mn and Co

CUI Xiang-Hao1, ZON Won-Ik2, WEI Chang-Ping3   

  1. 1. Department of Chemistry, Jilin University, Changchun 130023, China;
    2. Department of Chemistry, Natural Science Institute, Pyong Yang, Korea;
    3. Jilin Institute of Technology, Department Light Industry Textile Engineering, Changchun 130012, China
  • Received:1998-08-30 Online:1999-12-24 Published:1999-12-24

关键词: &beta, 相, 锰, 钴, FeSi2

Abstract: In this paper, p-type Fe1-xMnxSi2(x=0-0.12) and n type Fe1-yCoySi2(y=0-0.12) were synthesized by means of ceramic technology. The influence of additive amounts of Mn and Co, and heat treatment on the amounts of β-phase formed were studied. Experimental results indicate that addition of Mn and Co could inhibit the amounts and velocity of phase formation. High relative density(Dr) of p-type Fe1-xMnxSi2and n-type Fe1-yCoySi2causes excellent corrosion resistance and heat resistance which are beneficial for manufacture of thermoelectric components.

Key words: β-Phase, Mn, Co, FeSi2

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