高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (7): 1065.

• 论文 • 上一篇    下一篇

双[N,N'-亚烃基-2,2'-(芳亚甲基)二(3,4-二甲基吡咯-5-醛缩亚胺)]合双锰(Ⅱ)的合成、光谱特征及拟酶催化性能研究

陈新斌1, 桂明德1, 朱申杰1, 郭灿城2   

  1. 1. 南开大学化学系, 天津, 300071;
    2. 湖南大学化学化工系, 长沙, 410082
  • 收稿日期:1997-06-09 出版日期:1998-07-24 发布日期:1998-07-24
  • 通讯作者: 陈新斌,男,35岁,博士研究生.
  • 作者简介:陈新斌,男,35岁,博士研究生.
  • 基金资助:

    国家自然科学基金(批准号:29472055)资助课题.

Studies on Syntheses and Spectral Character of Bis[N,N'-alkylene-2,2-(arylmethylene)bis(3,4-dimethyl pyrrole-5-aldimino)] Dimanganese(Ⅱ) and Their Biomimetic Catalytic Character for the Monooxygenation of Cyclohexane with PhIO

CHEN Xin-Bin1, GUI Ming-De1, ZHU Shen-Jie1, GUO Can-Cheng2   

  1. 1. Department of Chemistry, Nankai University, Tianjin, 300071;
    2. Dept. of Chemistry and Chemical Engin. Hunan University, Changsha, 410082
  • Received:1997-06-09 Online:1998-07-24 Published:1998-07-24

PDF (PC)

被引次数

46

摘要： 首次报道了新型Schif碱类配体双[N,N-亚烃基-2,2-(苯亚甲基)二(3,4-二甲基吡咯-5-醛缩亚胺)]和双[N,N-(1,2-亚乙基)-2,2-(4-甲氧基苯亚甲基)二(3,4-二甲基吡咯-5-醛缩亚胺)]及其双锰配合物的合成方法、光谱特征及用配合物催化PhIO单加氧化环己烷反应的研究。

关键词: schiff碱, 合成, 光谱, 生物模拟催化, 氧化反应

Abstract: This paper first reports the syntheses and spectral character of bis[N,N'-alkylene-2,2-(phenylmethylene)bis(3,4-dimethylpyrrole-5-aldimine)](alkylenes: 1,3-propylene; 1,4-butylene; 1,2-phenylene; 4-methyl-1,2-phenylene), bis[N,N'-(1,2-ethylene)2,2-(4-methoxyphenylmethylene)bis(3,4-dimethylpyrrole-5-aldimine)] and their dimanganese(Ⅱ) complexes as well as the biomimetic catalytic properties of the complexes for the monooxygenation of cyclohexane with PhIO.

Key words: Schiff bases, Syntheses, Spectra, Biomimetic catalysis, Oxidation

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