高等学校化学学报

高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (3): 357.

• 研究简报 • 上一篇    下一篇

铁(Ⅱ)卟啉二胺配合物的合成和表征

钟新华1, 冯耀宇2, 黄杰生1, 申泮文1   

  1. 1. 南开大学化学系, 天津, 300072;
    2. 天津大学化学工程研究所, 天津, 300072
  • 收稿日期:1996-03-01 出版日期:1997-03-24 发布日期:1997-03-24
  • 通讯作者: 冯耀宇.
  • 作者简介:钟新华, 男, 24岁, 硕士研究生.
  • 基金资助:

    天津市21世纪青年科学基金

Synthesis and Characterization of Bis(amine) Iron(Ⅱ) Porphyrins

ZHONG Xin-Hua1, FENG Yao-Yu2, HUANG Jie-Sheng1, SHEN Pan-Wen1   

  1. 1. Department of Chemistry, Nankai University, Tianjin University, Tianjin, 300072;
    2. Institute of Chemical Engineering, Tianjin University, Tianjin, 300072
  • Received:1996-03-01 Online:1997-03-24 Published:1997-03-24

PDF (PC)

被引次数

4

关键词: 铁(Ⅱ)卟啉二胺, 胺, 合成

Abstract: Aseries of bis(amine) iron(Ⅱ) porphyrin Fe(Ⅱ)TPP(NH2R)2 complexes (NH2R=PhNH2, C6H11NH2, n-BuNH2, PhCH2NH2, NHMe2; TPP=dianion of meso-tetraphenylporphyrin) were prepared by the reduction of Fe (Ⅲ) porphyrins with the correspondingamine in an antiformin system in air as well as by the sodium borohydride reduction method,respectively.The complexes were charaterized by UV-Vis, IRand elementary analysis, andsome important properties of them were discussed.

Key words: Bis(amine)iron(Ⅱ) porphyrin, Amine, Synthesis

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