高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (8): 1225.

• 论文 • 上一篇    下一篇

1,1'-双[1-(芳亚氨基)乙基]二茂铁的合成及其环汞化反应

刘元红1, 吴养洁1, 贠红英1, 杨立2, 朱启秀2   

  1. 1. 郑州大学化学系, 郑州 450052;
    2. 兰州大学应用有机化学国家重点实验室
  • 收稿日期:1995-09-11 出版日期:1996-08-24 发布日期:1996-08-24
  • 通讯作者: 吴养洁
  • 作者简介:刘元红,女,24岁,助研.
  • 基金资助:

    国家自然科学基金

Synthesis and Cyclomercuration of 1,1'-Bis[1-(arylimino) ethyl] ferrocenes

LIU Yuan-Hong1, WU Yang-Jie1, YUN Hong-Ying1, YANG Li2, ZHU Qi-Xiu2   

  1. 1. Department of Chemistry, Zhengzhou University, Zhengzhou 450052;
    2. National Laboratory of Applied Organic Chemistry, Lanzhou University
  • Received:1995-09-11 Online:1996-08-24 Published:1996-08-24

摘要: 合成了11种1,1'-双[1-(芳亚氨基)乙基]二茂铁(简称二茂铁双亚胺)(la-1k)和8种环汞化反应产物,用元素分析、IR、1HNMR确定了它们的结构;除1c外,其余均为新化合物。双亚胺的环汞化反应表明主要生成单汞化产物,且汞化反应发生在取代茂环的邻位,但产率较低。探讨了影响环汞化反应的因素。

关键词: 1, 1'-双[1-(芳亚氨基)乙基]二茂铁, 合成, 环汞化反应

Abstract: Eleven kinds of 1,1'-bis[1-(arylimino)ethyl]ferrocenes 1 and eight kinds of mer curated products of 1,1'-bis[1-(arylimino)ethyl]ferrocene were synthesized.Their compositions and structures were confirmed by elementary analysis,IRand 1HNMR.All of them are new compounds except lc.The mercuration of compound 1 mainly produced the monoortho-mercurated products except 1b which only gave the bis-ortho-mercurated product.The yields are lower than that in the case of mono-ferrocenylketimines.The factors which influenced the mercuration were discussed.

Key words: 1,1-Bis[1-arylimino) ethyl]ferrocene, Synthesis, Cyclomercuration

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