高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (3): 310.

• 研究论文 • 上一篇    下一篇

[(Et4N)1.5{Li(H2O)6}0.5][Cd2(SC6H4But-4)6]·C2H5OH双核镉配合物的合成与晶体结构

汤卡罗, 李爱群, 金祥林, 唐有祺   

  1. 北京大学物理化学研究所, 北京 1000871
  • 收稿日期:1992-07-02 修回日期:1992-10-15 出版日期:1993-03-24 发布日期:1993-03-24
  • 通讯作者: 汤卡罗
  • 基金资助:

    国家自然科学基金

Synthesis and Crystal Structure of [Et4N)1.5{Li(H2O)6}0.5] [Cd2(SC6H4But-4)6]·EtOH

TANG Ka-Luo, LI Ai-Qun, JIN Xiang-Lin, TANG You-Qi   

  1. Institute of Physical Chemistry, Peking University, Beijing, 100871
  • Received:1992-07-02 Revised:1992-10-15 Online:1993-03-24 Published:1993-03-24

PDF (PC)

摘要： 标题化合物由4-Bu'S6H4SLi、Cd(NO3)2·4H2O和Et4NBr反应制备。用X射线单晶衍射法测定其晶体结构。

关键词: 双核镉配合物, 合成, 晶体结构, 4-叔丁基硫酚

Abstract: The title complex was synthesized and structurally characterized.The crystal belongs to the space group C2/c, α= 5.727(3) nm, 6= 1.2059(3) nm, c=2.5245(16) nm, β=101.39(5)°, V = 17.0921(5) nm3, Dc=l.178 g/cm, Z=8, R=0.076 for 4692 unique reflections [F≥4.0σ (F)].The cadmium is tetrahedral coordination with two terminal and two bridging ligands.The central M2S2 ring is planar and approximately rectangular.

Key words: Dinuclear cadmium complex, Synthesis, Crystal structure, 4-t-Butylthiophenol

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