高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (6): 735.

• 论文 • 上一篇    下一篇

过渡金属十一钨锆酸钾的合成及鉴定

王炜1, 朱秀华1, 刘景福2   

  1. 1. 大连铁道学院应用化学系, 大连, 116022;
    2. 东北师范大学化学系
  • 收稿日期:1991-07-10 出版日期:1992-06-24 发布日期:1992-06-24
  • 通讯作者: 王炜

Synthesis and Identification of Undecatungstozirconates with a Transition Metal

WANG Wei1, ZHU Xiu-hua1, LIU Jing-fu2   

  1. 1. Department of Applied Chemistry, Dalian Railway Institute, Dalian, 116022;
    2. Department of Chemistry, Northeast Normal University, Changchun
  • Received:1991-07-10 Online:1992-06-24 Published:1992-06-24

摘要: 缺位杂多阴离子XW11O39(X=Si,P,As,Ge)能与过渡金属阳离子M生成MXW11O39,在该混配杂多阴离子中,过渡金属原子占据缺位的八面体位置[1].为深入了解其配位方式,我们合成并鉴定了未见报道的Kn[MZrW11O39(H2O)]·xH2O(M为第一过渡系金属).

关键词: 钨锆杂多酸盐, 过渡金属, 合成

Abstract: The Kn[MZrW11O39]·xH2O(M=a metal from the first-row transition metals) were synthesized and identified by IR, UV, TG-DTA, XPS and Chemical analysis etc.

Key words: Tungstozirconates, Transition metals, Synthesis

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