高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (9): 942.

• 研究论文 • 上一篇    下一篇

极谱配位吸附波测定配合物表观稳定常数的方法研究

王晓平, 张祖训   

  1. 南京大学化学系
  • 收稿日期:1989-01-30 出版日期:1990-09-24 发布日期:1990-09-24
  • 通讯作者: 张祖训, 210008
  • 基金资助:

    国家自然科学基金

A Study on Method for Determination of Apparent Stability Constants of Complexes by Means of Polarographic Adsorptive-Coordinating Wave

Wang Xiaoping, Zhang Zuxun   

  1. Depwartment of Chemistry, Nanjing University, Nan jing
  • Received:1989-01-30 Online:1990-09-24 Published:1990-09-24

摘要: 对目前利用配位吸附波测定配合物表观稳定常数的常用方法进行了修正,提出了更具有普遍适用性的测定配合物表观稳定常数的理论公式,并对计算方法进行了探讨,获得了预期的满意的结果。

关键词: 极谱配位吸附波, 表观稳定常数, 配合物

Abstract: The common method for determining the apparent stability constants of complexes with po-larographic adsorptive-coordinating wave is modified, and a more generalized theoretical equation for the determination of the apparent stability constants of complexes is proposed. Approach.to the calculation is made. The good results are obtained as expected.

Key words: Polarographic adsorptive-coordinating wave, apparent stability constant, Complex

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