高等学校化学学报

高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (8): 787.

• 研究论文 •    下一篇

铁(Ⅲ)与2-[(邻羟苄叉)胺基]酚和吡啶混配配合物的合成、性质和结构

刘德信, 崔学桂, 耿芳东, 李风玲, 孔庆池   

  1. 山东大学化学系
  • 收稿日期:1987-12-14 出版日期:1989-08-24 发布日期:1989-08-24
  • 通讯作者: 刘德信

Synthesis, Properties and Structure of Mixed Ligand Complex of Iron(Ⅲ) with 2-[(o-Hydroxybenzylidene)amino] Phenol and Pyridine

Liu Dexin, Cui Xuegui, Geng Fangdong, Li Fengling, Kong Qingchi   

  1. Department of Chemistry, Shandong University, Jinan
  • Received:1987-12-14 Online:1989-08-24 Published:1989-08-24

PDF (PC)

被引次数

7

摘要： 合成了铁(Ⅲ)与2-[(邻羟苄叉)胺基]酚和吡啶混配配合物,通过四园衍射测定了配合物的结构。晶体属单斜晶系,空间群为C2/c.晶胞参数α=10.109(4)Å,b=23.403(7),c=18.417(3),β=102.20(2)°;V=4258.8Å3,Z=4,Dc=1.41g/cm3,μ=7.4cm-1(MoKa),F(000)=1872.用DTA和TG技术研究了配合物的热分解过程。

关键词: 铁, 配合物, 性质, 结构

Abstract: The mixed ligand complex of Fe(Ⅱ) with 2[(o-hydroxybenzylidene)amino] phenol and pyridine was prepared.Its structure was determined by means of four cycle diffractometer.It was found that the crystal belongs to the monoclinic system with space group C2/c, and the unit cell parameters are:a= 10.109(4)Å.6=23.403(7)Å.c= 18.417(3)Å, β=102.20(2)°, V = 4258.8 Å3,Z=4, Dc=1.41 g/cm3,μ=7.4 cm-1 (Mo Ka), F(000) = 1872.The process of its thermal decomposition was investigated by means of DTAand TGtechniques.

Key words: Iron, Coordination compound, Properties, Structure

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