高等学校化学学报

高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (7): 683.

• 研究论文 • 上一篇    下一篇

卟啉化合物研究(Ⅸ)——聚5-邻丙烯酰胺苯基-10,15,20-三苯基卟啉及其钴配合物的合成

李平英, 姜照慈, 黄素秋   

  1. 武汉大学化学系
  • 收稿日期:1987-11-07 出版日期:1989-07-24 发布日期:1989-07-24
  • 通讯作者: 李平英
  • 基金资助:

    国家自然科学基金

Study on Porphyrin Compounds (Ⅸ)——Synthesis of 5-(o-Propenoylaminophenyl)-10,15,20-Triphenyl Porphyrin Polymer and Its Cobalt Complex

Li Pingying, Jiang Zhaoci, Huang Suqiu   

  1. Department of Chemistry, Wuhan University, Wuhan
  • Received:1987-11-07 Online:1989-07-24 Published:1989-07-24

PDF (PC)

摘要： 将丙烯酰氯和5-邻氨基苯基-10,15,20-三苯基卟啉(Ⅰ)相连合成了5-邻丙烯酰胺苯基-10,15,20-三苯基卟啉(Ⅱ)。在引发剂作用下,Ⅱ进一步聚合,生成聚5-邻丙烯酰胺苯基-10,15,20-三苯基卟啉(Ⅲ),同时还合成了单体和聚合物的钴配合物。通过元素分析、核磁共振谱、红外光谱和可见吸收光谱对单体和聚合物的结构进行了鉴定。

关键词: 卟啉, 单体, 聚合物, 配合物

Abstract: 5- (o-propenoylaminophenyl)- 10, 15, 20-triphenylporphyrin (Ⅱ) was synthesized from acryloyl chloride and 5-(o-aminophenyl)-10,15, 20-triphenylporphyrin (Ⅰ) and was further polymerized to 5-(o-propenoylaminophenyl)-10,15,20-triphenylporphyrin polymer(Ⅲ) in the presence of initiator, and the cobalt complexes of (Ⅱ) and (Ⅲ) were also synthesized.Their chemical structures were identified by NMR, UVand IRspectra as well as elemental analysis.

Key words: Porphyrin, Monomer, Polymer, Complex

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