高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (4): 394.

• 论文 • 上一篇    下一篇

四氯化和四硝酸合双(4,4′-二甲基-2,2′-联吡啶)铈(Ⅳ)配合物的研究

朱文祥, 任颖杰, 赵继周   

  1. 北京师范大学化学系
  • 收稿日期:1986-10-21 出版日期:1988-04-24 发布日期:1988-04-24

Studies on the Tetranitrato-Bis(4,4'-Dimethyl-2,2'-Bipyridine)Cerium (Ⅳ) and Tetrachloro-Bis (4,4'-Dimethyl-2,2' -Bipyridine Hydrogen Chloride)Cerium(Ⅳ)

Zhu Wenxiang, Ren Yingjie, Zhao lizhou   

  1. Dept. of Chemistry, Beijing Normal University, Beijing
  • Received:1986-10-21 Online:1988-04-24 Published:1988-04-24

摘要: 在关于有机碱的(RH)2CeCl6型配合物的研究中,有许多报道称有机碱在配合物中不参与配位,只起中和酸的作用[1,2].

关键词: 四氯化铈, 硝酸铈(Ⅳ), 配合物, 4, 4&prime, -二甲基-2, 2&prime, -联吡啶

Abstract: Two title complexes were isolated. Spectroscopy studies show there is a similarity between the two complexes. The NMRspectrum suggests that the two nitrogen atoms in complex CeCl4(dmbipyHCl)2 are chemically non-equivalent. It may reveal the coordination of a nitrogen atom of bipyridine in that complex to the central ion.

Key words: Cerium tetrachloride, Cerium tetranitrate, Complexes, 4,4'-Dimethyl-2,2'-bipyridine

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