The Preparation and Property Studies of Transparent Resins Containing Rare Earth Terbium(Ⅲ) Complex

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (4): 695.

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The Preparation and Property Studies of Transparent Resins Containing Rare Earth Terbium(Ⅲ) Complex

WANG Dong-Mei¹, LIN Quan¹, FU Lian-She², LI Huan-Rong², CHU Zhen-Xing¹, YANG Bai¹

1. Key Laboratory of Supramolecular Structureand Spectroscopyof Educational Ministry, Depa rtment of Chemistry, Jilin University, Changchun 130023, China;
2. Changchun Institute of Applied Chemistry, State Kay Laboratoryof Rare Earth Chemistry and Physics, Chinese Academy of Sciences, Changchun 130022, China

Received:2000-09-14 Online:2001-04-24 Published:2001-04-24

Abstract

Abstract: The binary and ternary rare earth terbium(Ⅲ) complexes were introduced into the styrene/ α methylacrylic acid copolymerization system, and some optical resins that possess a high transparency in visible light region were obtained. The study of the optical property showed that they have good luminescent properties such as a high luminous intensity and a long luminous lifetime. In addition, we investigated the relationship among the transparency, the luminescent property of the copolymer, and the content of the components in the polymeric system. The results indicated that the optical resins can provide a relatively stable environment for composite rare earth complexes, which is good to exhibit the luminescent properties of rare earth complexes. At the same time, the rare earth complexes can offer the transparent resin a novel function.

Key words: Transparent resin, Rare earth complex, Optical property

CLC Number:

O631

TrendMD:

WANG Dong-Mei, LIN Quan, FU Lian-She, LI Huan-Rong, CHU Zhen-Xing, YANG Bai . The Preparation and Property Studies of Transparent Resins Containing Rare Earth Terbium(Ⅲ) Complex[J]. Chem. J. Chinese Universities, 2001, 22(4): 695.

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The Preparation and Property Studies of Transparent Resins Containing Rare Earth Terbium(Ⅲ) Complex

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