Preparation of Zn2In2S5 Photocatalyst by Post-treatment with Hydrochloric Acid for Effective Photocatalytic Hydrogen Evolution†

doi:10.7503/cjcu20200023

Abstract

Abstract:

ZnIn₂S₄ solid solutions were prepared by hydrothermal method and a series of Zn_mIn₂S_m₊₃(m=1—5, integer) solid solutions were obtained by post-treatment of ZnIn₂S₄ with HCl. The composition, structure and performance of the catalysts were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray photoelectron spectroscopy(XPS), UV-Visible diffuse reflective spectroscopy(UV-Vis DRS), photoluminescence(PL) spectroscopy and electrochemical tests. The visible light photocatalytic hydrogen production activity of a series of solid solutions was studied. It is found that ZnIn₂S₄ solid solution can be converted into Zn₂In₂S₅ solid solution after treatment with 0.5 mol/L HCl, and its hydrogen production activity is the highest, which is 2.2 times that of ZnIn₂S₄ solid solution. The catalyst also has good stability.

Key words: Zn_mIn₂S_m₊₃ solid solution, Hydrogen, HCl post-treatment, Photocatalysis

CLC Number:

O643

TrendMD:

PENG Shaoqin, LI Ziqin, HUANG Mingtao, LI Yuexiang. Preparation of Zn₂In₂S₅ Photocatalyst by Post-treatment with Hydrochloric Acid for Effective Photocatalytic Hydrogen Evolution^†[J]. Chem. J. Chinese Universities, 2020, 41(7): 1677.

Figures/Tables 9

References 25

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Sample	D/nm	S_BET/(m²·g^-1)	n_Zn:n_In:n_S	E_g/eV
ZIS	9.36	143.2	1:1.9:3.7	2.33
ZIS-0.25	9.37	131.2	—	2.34
ZIS-0.5	10.14	114.1	1:1.1:2.6	2.36
ZIS-0.75	11.13	88.7	—	2.39
ZIS-1.0	12.17	66.2	1:0.36:1.5	2.42

Sample	D/nm	S_BET/(m²·g^-1)	n_Zn:n_In:n_S	E_g/eV
ZIS	9.36	143.2	1:1.9:3.7	2.33
ZIS-0.25	9.37	131.2	—	2.34
ZIS-0.5	10.14	114.1	1:1.1:2.6	2.36
ZIS-0.75	11.13	88.7	—	2.39
ZIS-1.0	12.17	66.2	1:0.36:1.5	2.42

Preparation of Zn₂In₂S₅ Photocatalyst by Post-treatment with Hydrochloric Acid for Effective Photocatalytic Hydrogen Evolution^†

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