Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (4): 721.doi: 10.7503/cjcu20170652
• Physical Chemistry • Previous Articles Next Articles
ZHANG Wei1, ZHANG Yiwei1, LI Hui1,2, LEI Ming1,*()
Received:
2017-09-29
Online:
2018-04-10
Published:
2018-03-21
Contact:
LEI Ming
E-mail:leim@mail.buct.edu.cn
Supported by:
CLC Number:
TrendMD:
ZHANG Wei, ZHANG Yiwei, LI Hui, LEI Ming. Theoretical Study on the Formation Mechanism of Catalytic Active Components in Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by Transition Metal Cobalt Complex†[J]. Chem. J. Chinese Universities, 2018, 39(4): 721.
Fig.2 Structural parameters of (iPrPNP)CoCH3 complex at triplet(A) and singlet(B)For clarity H atoms of the (iPrPNP)CoCH3 complex are not shown. The values inside and outside the brackets represent the calculated data and experimental data, respectively. The symbol na indicates that the experimental data is unknown. Bond lengths are in nm, bond angles are in degree.
Fig.6 Key structural parameters of INT2', INT3', TS1 and TS3 complexs at triplet stateFor clarity, H atoms of the iPrPNP ligands and CH2SiMe3 are not shown. Bond lengths are in nm.
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