Synthesis of Thiocarbamates via Selenium-mediated Carbonylation of Aniline with Thiols

Chem. J. Chinese Universities

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Synthesis of Thiocarbamates via Selenium-mediated Carbonylation of Aniline with Thiols

ZHANG Xiao-Peng^1,2, LU Shi-Wei²*

1. College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, China;
2. National Engineering Research Center for Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116011, China

Received:2007-10-17 Revised:1900-01-01 Online:2008-06-10 Published:2008-06-10
Contact: LU Shi-Wei

Abstract

Abstract: In order to develop a new and facile route to the syntheses of thiocarbamates, selenium-mediated carbonylation of aniline with thiols was studied. Mediated by selenium, aniline reacted readily with carbon monooxide and thiols to afford thiocarbamates under the conditions of ambient temperature and atmospheric pressure. The results show that the reaction can proceed well to thiocarbamates in high yields with less hindered alkyl thiols. Selenium could be easily recovered and recycled.

Key words: Selenium, Aniline, Thiol, Carbonylation, Thiocarbamate

CLC Number:

O621.3

TrendMD:

ZHANG Xiao-Peng^1,2, LU Shi-Wei²*. Synthesis of Thiocarbamates via Selenium-mediated Carbonylation of Aniline with Thiols[J]. Chem. J. Chinese Universities, doi: .

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Synthesis of Thiocarbamates via Selenium-mediated Carbonylation of Aniline with Thiols

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