Synthesis of Nanometer Amino Acid Heteropoly Charge-transfer Complex (HPhe)3PMo12O40·2H2O by One Step Solid State Reaction at Room Temperature

Abstract

Abstract: A nanometer amino acid heteropoly charge-transfer complex was synthesized from Keggin structure phosphomolybdic acid (H₃PMo₁₂O₄₀·13H₂O) and phenylalanine(Phe) by one step solid state reaction at room temperature. The title compound was characterized by means of elemental analysis, IR, XRD, TEM, UV and CV. The results indicate that the sizes of the compound are in the range of 30-40 nm. The heteropoly anion still remains its Keggin structure in the product molecules. A sizeable electron-transfer interaction occurs between phosphomolybdic acid and phenylalanine. The electrochemical behavior of the compound in 1 mol/L H₂SO₄ shows that three redox waves correspond to three two-electron processes attributing to the reduction of PMo₁₂O₄₀^3- . Solid state reaction at room temperature is a convenient synthetic method for nanomaterials and may provide a new path to synthesize nanometer amino acid heteropoly complex.

Key words: Solid state reaction at room temperature, Nanometer, Amino acid, Heteropoly acid, Charge-transfer complex

CLC Number:

O614
O611.4

TrendMD:

WANG Rui-Ying, LIU Lang, JIA Dian-Zeng, LUO Jian-Min, FAN Zhao-Tian . Synthesis of Nanometer Amino Acid Heteropoly Charge-transfer Complex (HPhe)₃PMo₁₂O₄₀·2H₂O by One Step Solid State Reaction at Room Temperature[J]. Chem. J. Chinese Universities, 2004, 25(12): 2208.

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Synthesis of Nanometer Amino Acid Heteropoly Charge-transfer Complex (HPhe)₃PMo₁₂O₄₀·2H₂O by One Step Solid State Reaction at Room Temperature

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