Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H3cth] [Fe(CN)6]·3H2O

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (5): 663.

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Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H₃cth] [Fe(CN)₆]·3H₂O

GAO En-Qing¹, TANG Jin-Kui², LENG Xue-Bing¹, LIAO Dai-Zheng¹, JIANG Zong-Hui¹, YAN Shi-Ping¹

1. Department of Chemistry, Nankai University, Tianjin 300071, China;
2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:1999-09-24 Online:2000-05-24 Published:2000-05-24

Abstract

Abstract: Ahydrogen-bonded supramolecular compound, [H₃cth] [Fe(CN)₆]. 3H₂O, was synthesized from meso-5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane (cth) and K₃ [Fe (CN )₆]. The compound crystallizes in triclinic space group P1, with a=0. 93097 (9) nm, b=1. 05160(11) nm, c=1. 63847(17) nm, a=101. 077(2)°,β=90. 860(2)°, γ=111. 671 (2)°, V=1. 4564(3) nm³, Z=2, R=0.0415. The structure consists of neutral two-dimensional sheets assembled via hydrogen bonds be- tween the partially protonated macrocyclic tetraamine and the hexacyanoferrate(Ⅲ) ion, while the hydrogen bonds involving water molecules interlink the sheets to form a unique three-dimensional supramolecular architecture.

Key words: Supramolecule, Hydrogen bond, Macrocyclic compound, Crystal structure

CLC Number:

O641.4

TrendMD:

GAO En-Qing, TANG Jin-Kui, LENG Xue-Bing, LIAO Dai-Zheng, JIANG Zong-Hui, YAN Shi-Ping . Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H₃cth] [Fe(CN)₆]·3H₂O[J]. Chem. J. Chinese Universities, 2000, 21(5): 663.

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Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H₃cth] [Fe(CN)₆]·3H₂O

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