Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (5): 634.

• Articles • Previous Articles     Next Articles

Applying Molecular Mechanics, Molecular Graphics and Quantum Chemical Method to Study of Structure and Mechanism of Organic Reagent (Ⅱ)——GP Theory for Reaction Between Pyridyl Azo Organic Reagent and Metallic Ion

LAI Cheng-Ming1, NIU Shu-Qiang1, ZHANG Dong-Rui2, LIN Shao-Fan2   

  1. 1. Departmenl of Chemistry, Nankai University, Tianjin, 300071;
    2. Central Laboratory, Nankai University, Tianjin, 300071
  • Received:1991-12-31 Revised:1992-12-30 Online:1993-05-24 Published:1993-05-24

Abstract: In this paper, we have studied the mechanism of reaction between pyridyl azo organic reagents and metallic ions by means of GP Theory.It has been found that the reaction may be the charge control or orbital control, so there are two different coordinate positions.

Key words: Organic reagent, Action mechanism, GP theory

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