Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (2): 265.

• Articles • Previous Articles     Next Articles

The Raman Spectroelectrochemical Research for Li/SOCl2 Cell

ZHONG Fa-Ping1, YANG Han-Xi1, ZHA Quan-Xing1, SHENG Rong-Sheng2, XU Zhi-San2   

  1. 1. Department of Chemistry, Wuhan University, Wuhan, 430072;
    2. Analytical Center, Wuhan University, Wuhan
  • Received:1992-02-21 Revised:1992-11-09 Online:1993-02-24 Published:1993-02-24

Abstract: Amicro-Raman electrochemical cell was designed for in-situ study of the electroreduction of SOCl2 .The results suggest that S2Cl2 is the mediate product during the reducing of SOCl2 on carbon electrode.With the help of cyclic voltammetry, a reasonable mechanism of SOCl2 reducing on carbon electrode was derived.

Key words: Li battery, Raman spectrum, Electrochemistry

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