Mechanism of Electrochemical Capture of CO2 via Redox Cycle of 2-Amino-3-chloro-1,4-naphthoquinone in BMIMBF4

doi:10.7503/cjcu20190096

Abstract

Abstract: The mechanism of electrochemical capture of CO₂ via redox cycle of 2-amino-3-chloro-1,4-naphthoquinone(ACNQ) in 1-butyl-3-methylimidazolium tetrafluoroborate(BMIMBF₄) was investigated by cyclic voltammetry(CV) and in-situ Fourier transform infrared(FTIR) spectroelectrochemistry techniques. In the absence of CO₂, ACNQ undergoes a reversible two-step one-electron process in BMIMBF₄. The dianion(ACNQ^2-) formed during electrochemical reduction can be used as nucleophiles to attack the eletrophilic carbon center of CO₂ and form a stable CO₂ adduct when CO₂ is introduced. Furthermore, the stoichiometry of CO₂ electrochemical capture was evaluated. The result indicates that 1 mol of ACNQ^2- can capture 1 mol of CO₂. Also, the possible structures of CO₂ adducts in the reaction were calculated by the B3LYP method at the 6-311++G^** level.

Key words: in-situ FTIR spectroelectrochemistry, 2-Amino-3-chloro-1,4-naphthoquinone(ACNQ), 1-Butyl-3-methylimidazolium tetrafluoroborate, CO₂, Nucleophile

CLC Number:

O657.1

TrendMD:

QIAO Xuejiao, LI Dan, CHENG Longjiu, JIN Baokang. Mechanism of Electrochemical Capture of CO₂ via Redox Cycle of 2-Amino-3-chloro-1,4-naphthoquinone in BMIMBF₄[J]. Chem. J. Chinese Universities, 2019, 40(8): 1606.

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Mechanism of Electrochemical Capture of CO₂ via Redox Cycle of 2-Amino-3-chloro-1,4-naphthoquinone in BMIMBF₄

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