Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (4): 764.doi: 10.7503/cjcu20170413
• Physical Chemistry • Previous Articles Next Articles
ZHANG Yehua, JIANG Tao, LIU Shufeng, YU Yaqian, CHEN Yong*()
Received:
2017-06-28
Online:
2018-04-10
Published:
2018-02-12
Contact:
CHEN Yong
E-mail:yongchen@sit.edu.cn
Supported by:
CLC Number:
TrendMD:
ZHANG Yehua, JIANG Tao, LIU Shufeng, YU Yaqian, CHEN Yong. Ion Transfer of Leucovorin Ion Across the Membrane-modified Liquid/Liquid Interface†[J]. Chem. J. Chinese Universities, 2018, 39(4): 764.
Fig.1 CVs obtained at the W/DCH interface modified by HMSM-CTAB in the absence of calcium leucovorin(a) and in the presence of 0.8 mmol/L calcium leucovorin(b) at a scan rate of 20 mV/s
Fig.2 CVs obtained at the W/DCH interface modified by HMSM-CTAB in the absence of calcium leucovorin(dash line) and in the presence of 2 mmol/L calcium leucovorin(solid line) at different scan ratesFrom inner CVs to outer CVs, the scan rates are 20, 40, 60, 80 and 100 mV/s, respectively. Inset: the corresponding plot of peak current for calcium leucovorin from W to DCH against the square root of scan rate.
Fig.3 CVs obtained at the W/DCH interface modified by HMSM(A) and HMSM-CTAB(B) at a scan rate of 20 mV/sFrom inner CVs to outer CVs, the concentrations of calcium leucovorin are 0, 0.8, 1.2, 1.6, 2.0 and 2.4 mmol/L, respectively. Insets: the corresponding plots of peak current for the transfer of leucovorin ion from W to DCH vs. the concentration of calcium leucovorin in aqueous solution.
Fig.4 DPVs collected at the W/DCH interface modified by HMSM(A) and HMSM-CTAB(B) for different concentrations of calcium leucovorinFrom top to bottom, the concentrations of calcium leucovorin are 0, 0.8, 1.2, 1.6, 2.0, and 2.4 mmol/L, respectively.Insets: the corresponding plots of peak current for calcium leucovorin from W to DCH vs. the concentration of calcium leucovorin in aqueous solution.
Fig.5 Plots of Q vs. t1/2 and their asymptotesStep potential: (A) 0.70-0.46 V; (B) 0.70-0.47 V; (C) 0.70-0.48 V; (D) 0.70-0.49 V;(E) 0.70-0.50 V; (F) 0.70-0.51 V.
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