Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (12): 1740.

• Articles • Previous Articles     Next Articles

NMR and Quantum Chemical Studies of Tri(2 methyl 1-aziridinyl) Phosphine Oxide Isomers

HUA Shi-Ying1, GUO Chun-Xiao1, LUO Kui-De GAO2, Xin-Feng3   

  1. 1. Institute of Theoretical Chemistry, Department of Chemistry, Jilin University, Changchun, 130023;
    2. 9th Rese.Institute of Astronautical Ministry;
    3. Changchun Institute of Appl.Chem., Academia Sinica
  • Received:1993-01-12 Revised:1993-03-22 Online:1993-12-24 Published:1993-12-24

Abstract: 1H, 13C, 15N, 31Pand 17O NMRspectra of tri(2-methyl-1-aziridinyl) phosphine oxide were studied and simulated.The quantum chemical calculations on this compound were also carried out by AMIprogram.The optimized results show that there exist four kinds of isomers for the compound, two of them are enantiomer, and their geometrical configurations were obtained.

Key words: Tri(2-methyl-1-aziridinyl) phosphine oxide, Isomers, NMR

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