Kinetic study on Axial Coordination Faster Reaction of Tetra(p-sulfophenyl) porphyrin Iron(Ⅲ)

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (3): 382.

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Kinetic study on Axial Coordination Faster Reaction of Tetra(p-sulfophenyl) porphyrin Iron(Ⅲ)

ZHU Zhi-ang, LIANG Xin-yi, LIU Heng-qian, CHEN Rong-ti

Department of Chemistry, Nankai University, Tianjin, 300071

Received:1991-04-06 Online:1992-03-24 Published:1992-03-24

Abstract

Abstract: A kinetic study is reported for the axial coordination faster reaction of Tetra (p-sul-fophenyl) porphyrin iron (Ⅲ) (Fe(Ⅲ)TPPS₄)_D with ligands L [L=imidazole (Im)], 2-methylimidazole (MeIm), 2-ethyl-4-methylimidazole (EMIm)) in water by means of Union Giken RA-410 T-Jump spectrophotometer.

Key words: Tetra(p-sulfophenyl) porphyrin iron (Ⅲ), Axial coordination reaction, T-jump method, Reaction mechanism, Activation parameters

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ZHU Zhi-ang, LIANG Xin-yi, LIU Heng-qian, CHEN Rong-ti . Kinetic study on Axial Coordination Faster Reaction of Tetra(p-sulfophenyl) porphyrin Iron(Ⅲ)[J]. Chem. J. Chinese Universities, 1992, 13(3): 382.

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Kinetic study on Axial Coordination Faster Reaction of Tetra(p-sulfophenyl) porphyrin Iron(Ⅲ)

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