The Experimental Studies of SERS of Coadsorptive System on the Electrochemically Roughened Silver Electrode Surface

Abstract

Abstract: This paper presents the studies of the SERS spectra and their potential dependence for pyridine and benzole acid adsorbed on the electrochemically roughened silver surface in the pyridine/ben-zoic acid/KCl coexistent system. Their adsorption manners on the silver surface were also studied. Ex- perimental results show that there exist eoadsorptive and competitive adsorption between pyridine and benzole acid on the silver surface in the coexistent system. The competitive adsorption and their manners vary with the changing of the applied voltage.

Key words: Pyridine, Benzole acid, Surface enhanced Raman scattering (SERS), Coadsorption

TrendMD:

Gu Renao, Zong Yaping, Leng Yongzhang . The Experimental Studies of SERS of Coadsorptive System on the Electrochemically Roughened Silver Electrode Surface[J]. Chem. J. Chinese Universities, 1990, 11(8): 909.

[1]	CHANG Hui, YAO Shuangquan, HAN Wenjia, KANG Xiena, ZHANG Li, LI Xinping, ZHANG Zhao. Highly Solvatochromic Terpyridine Compounds for Identification of Butanol Isomers [J]. Chem. J. Chinese Universities, 2021, 42(3): 902.
[2]	YIN Shaoyun, ZHANG Luyin, WANG Zheng, PAN Mei. Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 646.
[3]	LIN Junjie, WANG Shuang, LI Weiqiang, CUI Xin, HUANG Chao. Efficient Synthesis of Pyridine ［2，3-d］pyrimidine Derivatives by Catalyst-free Tandem Cyclization Under Microwave Irradiation [J]. Chem. J. Chinese Universities, 2020, 41(12): 2749.
[4]	WANG Lin, ZHANG Yanhui, Arzugul Muslim, LAN Haidie. Morphology and Size Regulation of Polyaniline Induced by PS-b-P2VP as Template and Its Electrochemical Characters [J]. Chem. J. Chinese Universities, 2019, 40(8): 1748.
[5]	LIU Shufeng,QIU Haiyan,JIANG Tao,ZHANG Yehua,ZHAO Yun,CHENG Hanwen,CHEN Yong. Ion Transfer Behavior of Protonated Phenazopyridine at the Liquid/Liquid Interface Modified by Functionalized Hybrid Mesoporous Silica Membrane^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 973.
[6]	ZHAO Bangtun, TAO Jingjing, CHEN Xiaoji, FU Huimin, ZHU Weimin. Synthesis, Structure and Electrochemistry of Tetrathiafulvalene Vinylogues Bearing Thienyl and Pyridyl Groups^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1449.
[7]	MIAO Ruixiang,LIU Dongqing,REN Shun,ZHU Zexian,CHEN Yingbo,ZHANG Yufeng. Foams of Supramolecular Network Constructed by Poly(calixarene-piperazine) Amide and 2,2'-Bipyridine^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2327.
[8]	WANG Xiaochuang, ZHANG Jie, XIE Jianwei. Copper/Dodecyl Substituted Hydrazide-pyridine-N-oxide Catalyzed N-Arylation of Imidazoles with Aryliodides in Water^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1178.
[9]	ZHAO Bangtun, MA Shuxiu, TAO Jingjing, ZHU Weimin. Synthesis, Structures and Electrochemical Properties of Pyridine-based Tetrathiafulvalene Derivatives^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 193.
[10]	GAO Zhongzheng, YANG Liguo, BAI Dong, CHEN Lixia, TAO Zhu, XIAO Xin. Interaction of Inverted Cucurbit[7]uril with N,N'-dibenzyl -4,4'-pyridine Chloride^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 212.
[11]	ZHAO Lun, BAI Helong, SUN Erjun, WANG Xiaofeng, WANG Zichen. Synthesis and Characterization of Novel Ni(Ⅱ) Metal-organic Frameworks with Helical Crystal Structure^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1250.
[12]	ZHANG Yan, WANG Baolei, ZHAN Yizhou, ZHANG Liyuan, LI Yonghong, LI Zhengming. Synthesis and Biological Activities of Novel 5-(Pyridine-3-yl)-1,2,4-triazole Mannich Bases and Bis-Mannich Bases Containing Piperazine Moiety^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1100.
[13]	WEN Xing, TANG Liming, LIN Wanxin. Fabrication of Environmental Responsive Copolymer One-dimensional Nanostructures Using Metallogel Fibers as Template^† [J]. Chem. J. Chinese Universities, 2015, 36(1): 180.
[14]	ZHENG Huayan, ZHANG Riguang, LI Zhong. Theoretical Studies on the Interaction of CO and CH₃O on CuCl(111) Surface for Methanol Oxidative Carbonylation^† [J]. Chem. J. Chinese Universities, 2014, 35(9): 1926.
[15]	GAO Yuanhao, PAN Ruilong, TIAN Yupeng, LI Jing, ZHENG Zhi. Syntheses and Optical Properties of Two Novel Terpyridine Derivatives^† [J]. Chem. J. Chinese Universities, 2014, 35(7): 1439.

The Experimental Studies of SERS of Coadsorptive System on the Electrochemically Roughened Silver Electrode Surface

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments