Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (7): 1250.doi: 10.7503/cjcu20150903
• Articles: Inorganic Chemistry • Previous Articles Next Articles
ZHAO Lun1,2, BAI Helong1,2, SUN Erjun2, WANG Xiaofeng1,*(), WANG Zichen1
Received:
2015-11-26
Online:
2016-07-10
Published:
2016-06-16
Contact:
WANG Xiaofeng
E-mail:wangxf103@jlu.edu.cn
CLC Number:
TrendMD:
ZHAO Lun, BAI Helong, SUN Erjun, WANG Xiaofeng, WANG Zichen. Synthesis and Characterization of Novel Ni(Ⅱ) Metal-organic Frameworks with Helical Crystal Structure†[J]. Chem. J. Chinese Universities, 2016, 37(7): 1250.
Complex | 1 | 2 | 3 |
---|---|---|---|
CCDC No. | 1435639 | 1435783 | 1435640 |
Molecular formula | C64H60Ni2N10O15 | C50H36NiN4O8 | C88 |
Formula weight | 1322.61 | 879.54 | 1721.16 |
Crystal system | Monoclinic | Orthorhombic | Triclinic |
Space group | C2/c | Fdd2 | P |
a/nm | 2.2743(6) | 1.47100(15) | 1.1534(2) |
b/nm | 1.8062(5) | 4.9840(5) | 1.3067(2) |
c/nm | 1.8868(8) | 1.12261(11) | 1.4839(3) |
α/(°) | 90.00 | 90.00 | 104.106(4) |
β/(°) | 123.155(4) | 90.00 | 103.021(4) |
γ/(°) | 90.00 | 90.00 | 91.669(4) |
V/nm3 | 6.489(4) | 8.2303(14) | 2.1047(7) |
Z | 4 | 8 | 2 |
Dc/(Mg·m-3) | 1.354 | 1.416 | 1.355 |
F(000) | 2744 | 3632 | 900 |
GOF on F2 | 0.929 | 1.047 | 0.941 |
R1/wR2[I>2σ(I)] | 0.0713/0.1886 | 0.0639/0.1599 | 0.0909/0.2177 |
R1/wR2(all data) | 0.1385/0.2230 | 0.0934/0.1815 | 0.1972/0.2648 |
Table 1 Crystal data and structure refinement of complexes 1—3
Complex | 1 | 2 | 3 |
---|---|---|---|
CCDC No. | 1435639 | 1435783 | 1435640 |
Molecular formula | C64H60Ni2N10O15 | C50H36NiN4O8 | C88 |
Formula weight | 1322.61 | 879.54 | 1721.16 |
Crystal system | Monoclinic | Orthorhombic | Triclinic |
Space group | C2/c | Fdd2 | P |
a/nm | 2.2743(6) | 1.47100(15) | 1.1534(2) |
b/nm | 1.8062(5) | 4.9840(5) | 1.3067(2) |
c/nm | 1.8868(8) | 1.12261(11) | 1.4839(3) |
α/(°) | 90.00 | 90.00 | 104.106(4) |
β/(°) | 123.155(4) | 90.00 | 103.021(4) |
γ/(°) | 90.00 | 90.00 | 91.669(4) |
V/nm3 | 6.489(4) | 8.2303(14) | 2.1047(7) |
Z | 4 | 8 | 2 |
Dc/(Mg·m-3) | 1.354 | 1.416 | 1.355 |
F(000) | 2744 | 3632 | 900 |
GOF on F2 | 0.929 | 1.047 | 0.941 |
R1/wR2[I>2σ(I)] | 0.0713/0.1886 | 0.0639/0.1599 | 0.0909/0.2177 |
R1/wR2(all data) | 0.1385/0.2230 | 0.0934/0.1815 | 0.1972/0.2648 |
Fig.1 Coordination environment of the Ni(Ⅱ) ions(A), view of 2D sheets(B), the {42·63·8} topology net(C), 3D framework(D), the helical chains(E) and the opposite handedness in the A and B layers(F, G) The hydrogen atoms are omitted for clarity. Symmetry codes: #1: x-0.5, y-0.5, z; #2: -x+1.5, y-0.5, -z-0.5; #3: -x+1.5, y+0.5, -z-0.5; #4: x+0.5, y+0.5, z.
Fig.2 Coordination environment of the Ni(Ⅱ) ions(A), view of 3D framework(B, C), {48·54·63} topology net(D) and view of the helical chains(E) The hydrogen atoms are omitted for clarity.Symmetry codes: #1: -x+1.25, y+0.25, z+0.25; #2: -x+1.5, -y+0.5, z; #3: x, y, z+1; #4: x, y, z-1; #5: -x+1.25, y-0.25, z-0.25.
Fig.3 Coordination environment of the Ni(Ⅱ) ions(A), view of 2D wave-like sheets(B) and {44·62} topology net(C), schematic view of the 5-fold interpenetrating framework(D) and view of the helical chains(E) The hydrogen atoms are omitted for clarity. Symmetry codes: #1: x, y, z-1; #2: -x+2, -y-1, -z+2; #3: -x-1, -y, -z+1; #4: x, y, z+1.
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